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[1]王丹妮,黄 敏,柯 璇,等.磷尾矿资源化利用研究进展 [J].武汉工程大学学报,2026,48(03):237-245.[doi:10.19843/j.cnki.CN42-1779/TQ.202603014]
 WANG Danni,HUANG Min,KE Xuan,et al.Research progress on resource utilization of phosphate tailings [J].Journal of Wuhan Institute of Technology,2026,48(03):237-245.[doi:10.19843/j.cnki.CN42-1779/TQ.202603014]
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磷尾矿资源化利用研究进展
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
48
期数:
2026年03期
页码:
237-245
栏目:
磷化工论坛
出版日期:
2026-06-30

文章信息/Info

Title:
Research progress on resource utilization of phosphate tailings
文章编号:
1674 - 2869(2026)03 - 0237 - 09
作者:

武汉理工大学资源与环境工程学院,湖北 武汉 430070
Author(s):
WANG Danni HUANG Min KE Xuan BAO Shenxu*
School of Resource and Environmental Engineering,Wuhan University of Technology,Wuhan 430070,China
关键词:
磷尾矿有价元素建筑材料矿山充填农业应用
Keywords:

分类号:
TD926.4
DOI:
10.19843/j.cnki.CN42-1779/TQ.202603014
文献标志码:
A
摘要:
磷尾矿作为磷矿浮选过程的主要固体废弃物,蕴含丰富的有价组分,但受限于其物理化学惰性,目前整体综合利用率依然偏低。在“双碳”目标与绿色矿山建设背景下,探索磷尾矿的低碳、高效利用路径是缓解我国磷资源开发压力、实现生态与经济效益统一的关键。磷尾矿的资源化利用主要包括四个层面:有价元素的提取与回收、建筑材料的制备、矿山采空区的充填,以及农业领域土壤改良剂、肥料或保水剂的应用。然而,当前技术仍面临能耗高、成本与材料性能难以协同和附加值低等问题。未来研究应重点发展清洁高值化与多固废协同应用,突破低成本、低能耗的活化与梯级分离技术;同时完善环境安全与生态风险评估机制,保障体系的长期稳定性,促进磷尾矿的规模化消纳与全量化综合利用,实现生态环境保护与资源可持续利用。


Abstract:
Phosphate tailings are the primary solid waste generated during the phosphate rock flotation process and contain abundant valuable components. Nevertheless,restricted by their physicochemical inertness,the overall comprehensive utilization rate remains relatively low. Against the backdrop of the dual carbon goal and green mine construction,exploring low-carbon and high-efficiency utilization approaches for phosphate tailings is critical to alleviating the pressure of phosphorus resource exploitation in China and balancing ecological and economic benefits. Utilization approaches of phosphate tailings are mainly divided into four categories: extraction and recovery of valuable elements; preparation of building materials; backfilling of mine goafs; and application as soil amendments,fertilizers or water retaining agents in agriculture. However,existing technologies still suffer from high energy consumption,difficulty in balancing cost and material performance,and low added value of products. Future research should prioritize development of clean high-value utilization and collaborative disposal of multiple solid wastes,and make breakthroughs in low-cost and low-energy-consumption activation and cascade separation technologies. Meanwhile,it is necessary to improve the evaluation mechanism of environmental safety and ecological risks,guarantee long-term stability of the utilization system,promote large-scale disposal and comprehensive full-quantity utilization of phosphate tailings,and realize ecological environment protection and sustainable utilization of resources.


参考文献/References:

[ 1 ] 任飞,刘禹辰,刘佳,等. 我国磷化工产业现状与发展趋势:从资源驱动到创新引领[J]. 生态产业科学与磷氟工程,2026,41(2):6-12.
[ 2 ] 李睿,李智力,何东升,等. 磷尾矿土壤化应用研究现状及展望[J/OL]. 无机盐工业,2026-01-07.https://doi.org/10.19964/j.issn.1006-4990.2025-0335.
[ 3 ] LI X P,SHU J C,ZHAO H Y,et al. A critical review on approaches for phosphorus ore flotation tailings treatment and disposal technology:environment properties,comprehensive utilization,and resource utilization [J]. Industrial & Engineering Chemistry Research,2024,63(3):1191-1199.
[ 4 ] 杨效家,漆增连,李志兵,等. 磷尾矿资源肥料化利用途径研究进展[J]. 应用化工,2024,53(8):1932-1936.
[ 5 ] 赵鑫明,陈路路,柴佳琪,等. 磷化工副产物农业全量利用技术途径及研究进展[J]. 中国土壤与肥料,2025(9):239-247.
[ 6 ] 张晋,尤大海,李国栋,等. 磷尾矿基建筑材料研究进展与展望[J]. 非金属矿,2025,48(4):108-112.
[ 7 ] 王保明,王兴龙,杨英,等. 磷尾矿综合利用现状及研究进展[J]. 无机盐工业,2024,56(10):1-11.
[ 8 ] 朱秀雯,唐远,裴丰,等. 磷尾矿在农业领域的应用研究现状及展望[J]. 化学与生物工程,2024,41(1):1-7.
[ 9 ] JUN J D, HUANG X P, LIANG L L, et al. Research hotspot and trend of resource utilization of phosphorus tailings-based on Citespace and VOSviewer visualization [J]. Physicochemical Problems of Mineral Processing,2024,60(4):192132.
[10] YU Y H, DU C M. Leaching of phosphorus from phosphate tailings and extraction of calcium phosphates:toward comprehensive utilization of tailing resources [J]. Journal of Environmental Management,2023,347:119159.
[11] YU Y H,DU C M,ZHANG Y T,et al. Phosphorus recovery from phosphate tailings through a two-stage leaching-precipitation process:toward the harmless and reduction treatment of P-bearing wastes [J]. Environmental Research,2024,248:118328.
[12] YU Y H, DU C M, YANG X. Recovery of phosphorus from steelmaking slag and phosphate tailings by a collaborative processing method [J]. Separation and Purification Technology,2023,313:123499.
[13] ZHOU G Y, WANG N, GU H N, et al. Obtaining phosphorus concentrate from phosphate ore flotation tailings after Ca and Mg recovery using formic acid leaching [J]. Minerals Engineering,2025,232:109541.
[14] YIN L, DING S Y, ZHANG T, et al. Resource utilization of phosphate tailings through a novel strategy of sequential multi-separation processes [J]. Minerals Engineering,2026,237:110002.
[15] GU H N, ZHOU G Y, WEN H J, et al. Using of phosphoric acid to dissolve phosphate ore flotation tailings for stepwise separation of calcium and magnesium values [J]. Chemical Engineering Science,2025,307:121356.
[16] DING S Y,YIN L,ZHANG T,et al. Resource utilization of phosphate tailings by calcination and leaching with dilute H3PO4 solution [J]. Minerals Engineering,2025,222:109172.
[17] MA Z L, LI D K,YUE S W, et al. Separation of calcium and magnesium from phosphorus tailings by the integrated CO2 absorption-mineralization process [J]. Separation and Purification Technology,2025,364(Part 3):132534.
[18] 金会心,王华,李军旗,等. 新华含稀土磷矿浮选实验研究[J]. 过程工程学报,2008(3):453-459.
[19] LIANG H J,ZHANG P,JIN Z,et al. Processing of a phosphate flotation tails for recovery of rare earths and phosphate [J]. Minerals,2025,15(9):900.
[20] 沈凡,韦国苏,谯理格,等. 磷尾矿陶粒烧结工艺优化及其轻质超高强混凝土配制[J]. 桂林理工大学学报,2022,42(3):717-724.
[21] FU F H, HU N Y, YANG S W, et al. Influence of different factors on phase evolution,pore morphology and properties of phosphate tailings foamed ceramics prepared by foaming gel casting [J]. Ceramics International,2025,51(1):165-178.
[22] ZHAO H,MAO Y S,JIANG M T,et al. Sustainable production of lightweight ceramics from shield tunnel muck and phosphorus tailings enhanced by CaO/SiO2 ratios [J]. Construction and Building Materials,2025,482:141738.
[23] XIAO T T,FAN X Y,ZHOU C Y,et al. Preparation of ultra-lightweight ceramsite from waste materials:using phosphate tailings as pore-forming agent [J]. Ceramics International,2024,50(9):15218-15229.
[24] FU F H,HU N Y,YANG S W, et al. Conversion of recovered phosphorus tailings into high-value lightweight ceramic materials and evaluation of environmental safety [J]. Process Safety and Environmental Protection,2024,192:1356-1366.
[25] 侯代文,梁欢,邢丽静,等. 响应面优化浮选磷尾矿制备陶粒及其对磷的吸附研究[J]. 无机盐工业,2025,57(11):74-82.
[26] JIANG L L,LI J Q,ZHANG Q G,et al. Influence of phosphorus tailings fineness on the hydration process and physical properties of ordinary Portland cement [J]. Construction and Building Materials,2024,417:135349.
[27] 姜立龙,李剑秋,杨林,等. 高镁磷尾矿作为矿物掺合料应用于混凝土性能研究[J]. 无机盐工业,2024,56(1):90-95.
[28] 卜娜蕊,江伟,吕浩璋,等. 掺磷尾矿配制C40混凝土的力学性能试验研究[J]. 新乡学院学报,2024,41(6):55-59.
[29] 王杨盛,周晗,庄心善,等. 磷尾矿粉-钢纤维混凝土抗渗与力学性能[J]. 混凝土,2026(1):11-15.
[30] LIU Y J,HU N Y,YANG S W,et al. The hydration behavior and foaming mechanism of foamed concrete prepared by substantial amounts of phosphate tailings [J]. Construction and Building Materials,2025,472:140799.
[31] GU K,CHEN B,YAN P,et al. Recycling of phosphate tailings and acid wastewater from phosphorus chemical industrial chain to prepare a high value-added magnesium oxysulfate cement [J]. Journal of Cleaner Production,2022,369:133343.
[32] CHEN Q S, ZHANG Q L, FOURIE A, et al. Utilization of phosphogypsum and phosphate tailings for cemented paste backfill [J]. Journal of Environmental Management,2017,201:19-27.
[33] HAN Y D, LIU L, RUAN S S, et al. Study on processability,hydration characteristics and solidification mechanism of hazardous elements of high-phosphorus solid waste paste backfill materials [J]. Journal of Environmental Chemical Engineering,2025,13(5):117816.
[34] YANG J, LIU S Y ,HE X Y, et al. Fluid-related performances and compressive strength of clinker-free cementitious backfill material based on phosphate tailings [J]. Fluid Dynamics & Materials Processing,2024,20(9):2077-2090.
[35] 叶峰,李延杰,张文龙,等. 尾泥对高浓度磷尾矿胶结充填材料性能影响研究[J]. 矿业研究与开发,2018,38(3):69-72.
[36] 刘冬梅,卢希,高德军. 掺固硫灰水泥胶结磷尾矿充填料浆流变性能[J]. 中国矿业,2020,29(5):126-130,148.
[37] 王昊,邱跃琴,龙文江,等. 磷尾矿充填中有害元素地下迁移规律研究[J]. 矿冶工程,2019,39(5):87-91.
[38] 黄远来,邱跃琴,高贺然. 磷尾矿充填料浆有害离子固化试验研究[J]. 矿业研究与开发,2016,36(12):93-96.
[39] 郑宗雨,李智力,何东升,等. 热活化磷尾矿制备钙镁硅土壤调理剂实验研究[J]. 生态产业科学与磷氟工程,2026,41(1):26-32.
[40] 吕继良,王振,李智力,等. 磷尾矿基土壤调理剂与固氮解磷菌配施对土壤改良效果的影响[J]. 化学与生物工程,2026,43(4):62-70.
[41] CHEN B J, JIN C Y, YANG J Q, et al. Synergistic organic manure treatment with Al/Fe/Ca-based fluoride-fixing agents promote soil formation and utilization of phosphate flotation tailings [J]. Process Safety and Environmental Protection,2024,192:495-509.
[42] VEN?L?INEN S H,NOUSIAINEN A,KANERVA S. The potential of phosphate mine tailings in the remediation of acidic Pb-contaminated soil [J]. Soil & Environmental Health,2024,2(4):100112.
[43] DENG S N,HOU Y W,LIU Z,et al. Novel thermal modification of phosphate tailings for enhanced heavy metals immobilization in soil [J]. Environmental Research,2025,286(Part 1):122796.
[44] DAI L M,LI J H,ZHANG J X,et al. Development and mechanistic study of phosphate tailings based soil heavy metal prophylactic agents with encapsulated structure for lead stabilization and phosphorus speciation in soils [J]. Journal of Environmental Management,2025,373:123578.
[45] DAI L M,LI J H,ZHANG J X,et al. The Pb capture mechanism of soil prophylactic agents prepared from phosphorus tailings and the influence of phosphorus speciation on its slow-release mechanism [J]. Science of the Total Environment,2024,955:176996.
[46] ZHANG J X, DAI L M,LI J H, et al. Phosphate tailings-based slow-release heavy metal passivation materials:mechanism,environmental risk,and microbial community evolution [J]. Journal of Cleaner Production,2024,434:139931.
[47] 吴珊珊,刘意章,周旺旺,等. 磷尾矿钝化材料研制及其对土壤重金属的修复机制[J]. 矿物学报,2024,44(3):326-334.
[48] 郑建国,于南树,刘永秀,等. 磷酸活化磷尾矿制取聚合态钙镁磷肥的工艺条件研究[J]. 无机盐工业,2020,52(2):43-46.
[49] 杨大润,孙玉翠,李莹莹,等. 基于磷尾矿和湿法磷酸淤渣的钙镁颗粒肥料制备[J]. 化工矿物与加工,2025,54(10):52-58.
[50] XIE Y X,ZHANG Q,YUAN D Y,et al. Develop-ment and characterization of phosphate tailings-based humic acid slow-release fertilizer using ball milling sludge acid activation [J]. Process Safety and Environmental Protection,2025,202(Part A):107665.
[51] CHEN Z Q, WANG F, NIU G Q, et al. Design and process regulation of CaO-SiO2-MgO-P2O5 based glass fertilizer from direct thermal activation of low-grade phosphate ore and phosphate tailings [J]. Phosphorus,Sulfur,and Silicon and the Related Elements,2025,200(1):77-89.
[52] 孙鹏,余赟,张汉卿,等. 磷尾矿在复合肥中的应用研究[J]. 磷肥与复肥,2024,39(2):20-22.
[53] GENG C X, MA X L, HOU X F,et al. Regulatory mechanism of phosphorus tailings and organic fertilizer jointly driving the succession of acidic soil microbial functional groups and enhancing corn yield [J]. Agriculture,2025,15(19):2011.
[54] GENG C X,SHI H E,WANG J H,et al. Research on utilizing phosphorus tailoring recycling to improve acidic soil:the synergistic effect on crop yield,soil quality,and microbial communities [J]. Plants,2025,14(22):3475.
[55] 王景文,杨效家,张琦,等. 磷尾矿基钙镁缓释肥料对小白菜的应用效果研究[J]. 西南农业学报,2025,38(8):1616-1623.
[56] 龚雯茜,李萍,魏骊达,等. 保水剂改良黄土与植物根系的水势响应机制研究[J]. 水文地质工程地质,2026,53(1):277-284.
[57] 王雪郦,邱树毅. 含磷农用保水剂的制备及性能研究[J]. 中国农学通报,2011,27(7):284-289.
[58] 王毓,王身玉,陈洪事,等. 新型含磷温敏智能保水剂的制备及性能[J]. 江苏农业科学,2015,43(6):353-355,443.

相似文献/References:

备注/Memo

备注/Memo:
稿日期:2026-03-27
基金项目:地球深部探测与矿产资源勘查国家科技重大专项(2025ZD1010806);湖北省技术创新专项(2025BCB038);中央高校基本科研业务费(104972025KFYgx0002)
作者简介:王丹妮,硕士研究生。Email:dnwang2025@163.com
*通信作者:包申旭,博士,教授。Email:sxbao@whut.edu.cn


更新日期/Last Update: 2026-06-26