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[1]胡学雷,肖莉,王银平,等.杂合物(H2en)［Mo3O10］的水热合成与晶体结构[J].武汉工程大学学报,2010,(07):37-38.[doi:10.3969/j.issn.16742869.2010.07.009]
　HU Xue lei,XIAO Li,WANG Ying ping,et al.Hydrothermal synthesis and crystal structure ofan organicinorganic hybrid (H2en)［Mo3O10］[J].Journal of Wuhan Institute of Technology,2010,(07):37-38.[doi:10.3969/j.issn.16742869.2010.07.009]
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杂合物(H2en)［Mo3O10］的水热合成与晶体结构(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2010年07期
页码:
37-38
栏目:
化学与化学工程
出版日期:
2010-07-31

文章信息/Info

Title:
Hydrothermal synthesis and crystal structure of
an organicinorganic hybrid (H2en)［Mo3O10］
文章编号:
16742869(2010)07003702
作者:
胡学雷; 肖莉; 王银平; 王小波
武汉工程大学化工与制药学院，绿色化工过程省部共建教育部重点实验室，
湖北省新型反应器与绿色化学工艺重点实验室，湖北 武汉 430074
Author(s):
HU Xuelei; XIAO Li; WANG Yingping; WANG Xiaobo
School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology；Key Laboratory for Green Chemical Process
of Ministry of Education, Hubei Key Lab of Novel Reactror and Green Chemical Technology,Wuhan 430074, China
关键词:
有机—无机杂合物; 多金属氧酸盐; 水热法; 晶体结构
Keywords:
organicinorganic hybrid;  polyoxometalate;  hydrothermal method;  crystal structure
分类号:
O641.4
DOI:
10.3969/j.issn.16742869.2010.07.009
文献标志码:
A
摘要:
以(NH4)3PMo12O40，乙二胺(en)，CuCl2·2H2O为原料通过水热法合成得到了标题配合物.晶体结构分析表明配合物属单斜晶系，P2(1)/n空间群，晶胞参数为a=0.808 19(6) nm，b=1.445 69(11) nm，c=0.891 84(7) nm，α=90.00 °，β=98.134 0(10) °，γ=90.00 °，V=1.031 54(14) nm3，Z=4，R=0.033 5，wR=0.064 7.配合物由［Mo3O10］2-与(H2en)2+组成，［Mo3O10］2-由共边和共面的MoO6八面体连接而成，呈无限链状结构，链与链之间由(H2en)2+通过氢键连接成层状结构.
Abstract:
 The title complex was hydrothermally synthesized from (NH4)3PMo12O40,CuCl2·2H2O and en(ethylenediamine).Xray structural analyses reveal that the compound crystallizes in the monoclinic system and space group P2(1)/n, with a= 8.081 9(6) nm,b=14.456 9(11) nm,c=8.918 4(7) nm,α=90.00 °，β=98.134 0(10) °,γ=90.00 °,V=1 031.54(14) nm3,Z=4,R=0.033 5,wR=0.064 7.Its structure consists of infinite chains made up of distorted MoO6 octahedra, which is connected by edges and faces.The chains are linked into layers by ethylenediamine cations through hydrogen bonds.

参考文献/References:

［1］Bellitto C, Bauer E M, Righini G.On the crystal structures and some hybrid organicinorganic organophsphonates［J］.Inorg Chim Acta,2008,361(14):37853799．
［2］吴华东，明娟，张海燕，等.一个新的三环铜配合物的晶体结构研究［J］.武汉工程大学学报,2009,31(5):1113．
［3］Ma H Y, Wu L Z, Pang H J,et al.Hydrothermal synthesis of two Anderson POMsupported transition metal organicinorganic compounds［J］.Journal of Molecular Structure,2010,967(1):1519．
［4］王恩波,胡长文,许林.多酸化学导论［M］.北京:化学工业出版社,1998:6775．
［5］Qi Y F,Li Y G,Qin C,et al.From chain to network: design and analysis of novel organicinorganic assemblies from organically functionalized zincsubstituted polyoxovanadates and zinc organoamine subunits［J］.Inorg Chem, 2007,46:32173230．
［6］Bruker.SMART, SAINT, SADABS and SHELXTL.version 6.10Madison:Bruker AXS Inc，2000．
［7］Ding C, Lin B Z, Han G H, et al.Poly ［propane1,3diammonium ［tetraμ3oxohexaoxotrimolybdenum(VI)］ dihydrate］［J］.Acta Crystallographica Section C,2007,63:256258．

相似文献/References:

[1]靳素荣,袁军,张联盟.（dienH3）2P2Mo5O23的非等温热解动力学研究[J].武汉工程大学学报,2008,(02):38.
　JIN Su rong,YUAN Jun,ZHANG Lian meng.Research on the nonisothermal decomposition kinetics ofpolyoxometallate （dienH3）2P2Mo5O23[J].Journal of Wuhan Institute of Technology,2008,(07):38.

备注/Memo

备注/Memo:

本文编辑：张瑞收稿日期：20100419作者简介：胡学雷（1967），教授，博士，硕士研究生导师.研究方向：配位化学.
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