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[1]孙春英,黄勉如,李 亮,等.碳化硅纳米颗粒/聚吡咯复合气凝胶的制备与性能研究[J].武汉工程大学学报,2025,47(03):298-304.[doi:10.19843/j.cnki.CN42-1779/TQ.202404021]
　SUN Chunying,HUANG Mianru,LI Liang,et al.Preparation and properties of silicon carbide nanoparticles/polypyrrole composite aerogels[J].Journal of Wuhan Institute of Technology,2025,47(03):298-304.[doi:10.19843/j.cnki.CN42-1779/TQ.202404021]
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碳化硅纳米颗粒/聚吡咯复合气凝胶的制备与性能研究
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
47
期数:
2025年03期
页码:
298-304
栏目:
现代大化工
出版日期:
2025-06-30

文章信息/Info

Title:
Preparation and properties of silicon carbide nanoparticles/polypyrrole composite aerogels
文章编号:
1674 - 2869（2025）03 - 0298 - 07
作者:
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
School of Materials Science and Engineering，Wuhan Institute of Technology，Wuhan 430205，China
关键词:
Keywords:
分类号:
TP212；TQ427.26
DOI:
10.19843/j.cnki.CN42-1779/TQ.202404021
文献标志码:
A
摘要:
为了推进新能源的开发利用和实现能源的可持续发展，可利用电化学和光热转换技术对能源进行存储和转化。本文采用原位氧化聚合法，在低温条件下以九水硝酸铁为氧化剂将吡咯单体在碳化硅纳米颗粒表面进行聚合，通过控制反应时间和搅拌速度实现聚吡咯有效包覆，最后通过冷冻干燥得到碳化硅纳米颗粒/聚吡咯复合气凝胶。通过扫描电子显微镜、X射线衍射、傅里叶变换红外光谱、电化学测试和水蒸发实验等探究了复合气凝胶与聚吡咯气凝胶之间的性能差异，以及吡咯与碳化硅纳米颗粒的质量比对复合气凝胶的形貌、电化学性能和光热蒸发性能的影响规律。结果表明：碳化硅纳米颗粒与吡咯质量比为12.0∶193.8的复合气凝胶的电化学与光热性能最佳。该复合气凝胶在1 A·g-1的电流密度下的比电容为216.9 F·g-1，在200 mV·s-1的扫描速率下进行1 000次循环伏安测试后的比电容保持率为95.0%，其电化学性能与聚吡咯气凝胶相比有明显提升；1 kW·m-2光照强度下，复合气凝胶在模拟海水中的蒸发速率可达1.98 kg·m-2·h-1，而且在相同条件下进行12次光热循环后，其蒸发速率保持在1.98~2.03 kg·m-2·h-1范围内。
Abstract:
Electrochemical and photothermal conversion technologies are used for energy storage and conversion to promote the development and utilization of new energy and achieve sustainable energy development. In this study，an in situ oxidative polymerization method was used to polymerize pyrrole monomer on the surface of silicon carbide nanoparticles at low temperature using ferric nitrate hydrate as oxidant. And homogeneous encapsulation of polypyrrole was achieved by controlling the reaction time and stirring speed. The composite aerogels of silicon carbide nanoparticles/polypyrrole were obtained by freeze-drying. The performance differences between the composite aerogels and polypyrrole aerogels, as well as the effects of the mass ratio of pyrrole to silicon carbide nanoparticles on the morphology, electrochemical properties, and photothermal evaporation properties of the composite aerogels, were explored with scanning electron microscopy, X-ray diffraction，Fourier transform infrared spectroscopy, electrochemical tests, and water evaporation experiments. The results showed that the composite aerogel with a mass ratio of silicon carbide nanoparticles to pyrrole of 12.0∶193.8 has the best electrochemical and photothermal properties. The specific capacitance of the composite aerogel was 216.9 F·g-1 at a current density of 1 A·g-1，and the retention rate of the specific capacitance was 95.0% after 1 000 cyclic voltammetry tests at a scan rate of 200 mV·s-1. Its electrochemical performance was significantly improved compared with that of the polypyrrole aerogel. Under a light intensity of 1 kW·m-2，the evaporation rate of the composite aerogel in simulated seawater could reach 1.98 kg·m-2·h-1. And after 12 photothermal cycles under the same conditions，its evaporation rate remained in the range of 1.98－2.03 kg·m-2·h-1.

参考文献/References:

[1] MARADIN D. Advantages and disadvantages of renewable energy sources utilization [J]. International Journal of Energy Economics and Policy，2021，11（3）：176-183.
[2] LI C，JIN S，ARCHER L A，et al. Toward practical aqueous zinc-ion batteries for electrochemical energy storage [J]. Joule，2022，6（8）：1733-1738.
[3] 陈晓敏，徐丹，魏影，等.过渡金属纳米异质材料在超级电容器中的应 [J].应用技术学报，2024，24（3）：266-275，315.
[4] ZHANG Y，MEI H X，CAO Y，et al. Recent advances and challenges of electrode materials for flexible supercapacitors [J]. Coordination Chemistry Reviews，2021，438：213910.
[5] ACHARYA J，OJHA G P，PANT B，et al. Construction of self-supported bimetallic MOF-mediated hollow and porous tri-metallic selenide nanosheet arrays as battery-type electrodes for high-performance asymmetric supercapacitors [J]. Journal of Materials Chemistry A，2021，9（42）：23977-23993.
[6] CUI X M，RUAN Q F，ZHUO X L，et al. Photothermal nanomaterials：a powerful light-to-heat converter [J]. Chemical Reviews，2023，123（11）：6891-6952.
[7] CAI Y H， WU J F， SHI S Q， et al. Advances in desalination technology and its environmental and economic assessment [J]. Journal of Cleaner Production，2023，397：136498.
[8] 张鹏，方龙，杜寒威，等.三聚氰胺海绵基太阳能蒸发器的研究进展 [J].武汉工程大学学报，2023，45（6）：599-605.
[9] 周彬，鄢莹，田源灏，等.多功能聚吡咯/聚酰亚胺电磁屏蔽复合膜的制备与性能研究[J].包装工程，2024，45（9）：261-269.
[10] 黄天龙，杜寒威，魏端丽，等.多功能聚吡咯复合水凝胶传感器的制备与性能研究[J].武汉工程大学学报，2022，44（6）：629-635.
[11] SONG Y， SHANG M J， LI J G， et al. Continuous and controllable synthesis of MnO2/PPy composites with core-shell structures for supercapacitors [J]. Chemical Engineering Journal，2021，405：127059.
[12] ZESHAN M， ZEESHAN M， SHERIF E S M，et al. Synergistic enhancement of electromagnetic wave absorbance in spinel ferrite-polypyrrole composites [J]. Applied Nanoscience，2023，13（6）：4651-4659.
[13] MENG L S， YANG S， MA Y， et al. Porous polypyrrole nanotube-based organohydrogels：versatile materials for robust electromagnetic interference shielding in harsh environments [J]. Chemical Engineering Journal，2024，479：147643.
[14] WANG Z， YAN Y T， SHEN X P， et al. A wood-polypyrrole composite as a photothermal conversion device for solar evaporation enhancement [J]. Journal of Materials Chemistry A，2019，7（36）：20706-20712.
[15] ZHENG Y Y， XU J， YANG X S， et al. Decoration NiCo2S4 nanoflakes onto PPy nanotubes as core-shell heterostructure material for high-performance asymmetric supercapacitor [J]. Chemical Engineering Journal，2018，333：111-121.
[16] 刘斐，米舒，张金洋，等. CO2可逆溶剂中原位复合聚吡咯制备纤维素基光热转换气凝胶材料研究 [J]. 化工新型材料，2023，51（11）：151-156.
[17] CHOUDHARY R B， ANSARI S， PURTY B. Robust electrochemical performance of polypyrrole（PPy） and polyindole（PIn） based hybrid electrode materials for supercapacitor application：a review [J]. Journal of Energy Storage，2020，29：101302.
[18] EL NADY J， SHOKRY A， KHALIL M， et al. One-step electrodeposition of a polypyrrole/NiO nanocomposite as a supercapacitor electrode [J]. Scientific Reports，2022，12（1）：3611.
[19] WU Y Z， SHEN L， ZHANG C X， et al. Polyacid doping-enabled efficient solar evaporation of polypyrrole hydrogel [J]. Desalination，2021，505：114766.
[20] WANG X H， WU Z X， CHEN Z K， et al. Effect of preform structure on mechanical and thermal properties of SiCf/SiC composites [J]. Journal of Central South University，2024，31（1）：101-113.
[21] CHANG H W，TSAI Z Y， YE J J， et al. Synthesis and characterization of Ni-Co-O nanosheets on silicon carbide microspheres/graphite composite for supercapacitor applications [J]. C，2023，9（4）：101.
[22] ZHANG Z H，TAN J， CHENG L S， et al. In-situ growth of silicon carbide nanofibers on carbon fabric as robust supercapacitor electrode [J]. Ceramics International，2021，47（17）：24652-24662.
[23] TANG Q， CHEN X Y， ZHOU D L，et al. Biomass-derived hierarchical porous carbon/silicon carbide composite for electrochemical supercapacitor [J]. Colloids and Surfaces A：Physicochemical and Engineering Aspects，2021，620：126567.
[24] NGUYEN T K， ABEROUMAND S， DAO D V. Advances in Si and SiC materials for high-performance supercapacitors toward integrated energy storage systems [J]. Small，2021，17（49）：2101775.
[25] OJHA G P， KANG G W， KUK Y S， et al. Silicon carbide nanostructures as potential carbide material for electrochemical supercapacitors：a review [J]. Nanomaterials，2023，13（1）：150.
[26] WANG X G， ZHANG C Y，WANG K，et al. Highly efficient photothermal conversion capric acid phase change microcapsule：silicon carbide modified melamine urea formaldehyde [J]. Journal of Colloid and Interface Science，2021，582（Part A）：30-40.
[27] LIU Y Y，JIA L N，WANG W B，et al. Effect of Ni content on the wear behavior of Al-Si-Cu-Mg-Ni/SiC particles composites [J]. International Journal of Minerals，Metallurgy and Materials，2024，31（2）：374-383.
[28] YIN X G， LIU X Y， LI H， et al. Photocatalytic degradation of rhodamine B by recyclable AgBr/polypyrrole（PPy）nano-catalysts [J]. Journal of Wuhan University of Technology（Materials Science Edition），2023，38（5）：1198-1204.
[29] 邱海鹏，关星宇，徐俊杰，等. 基体改性对SiC/SiC复合材料高温抗氧化性能的影响[J]. 现代技术陶瓷，2023，44（3）：183-192.
[30] 温书宝，郭家铭，马小悦，等.聚吡咯涂覆碳纤维的制备及其复合材料的力学性能研究 [J]. 化工新型材料，2023，51（11）：123-127，137.
[31] LIU R N，SUN S X，ZHONG R Q，et al. Nitrogen-doped microporous carbon coated on carbon nanotubes for high performance supercapacitors [J]. Microporous and Mesoporous Materials，2020，305：110300.


相似文献/References:

备注/Memo

备注/Memo:
收稿日期：2024-04-15
基金项目：国家自然科学基金（U24A20554）；湖北省重点研发专项（2023BAB100）；贵州省重大专项（黔科合重大专项字［2024］012）
作者简介：孙春英，硕士研究生。Email：2445617296@qq.com
*通信作者：季家友，博士，教授。Email：Jijy@wit.edu.cn
引文格式：孙春英，黄勉如，李亮，等. 碳化硅纳米颗粒/聚吡咯复合气凝胶的制备与性能研究［J］. 武汉工程大学学报，2025，47（3）：298-304.
更新日期/Last Update: 2025-07-09