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[1]杨平,李兰芳,蔡惠,等.双酚A在聚茜素红/碳纳米管电极上的伏安行为[J].武汉工程大学学报,2010,(11):18-21.[doi:10.3969/j.issn.16742869.2010.11.005]
　YANG Ping,LI Lan fang,CAI Hui,et al.Voltammetric behavior of bisphenol A on poly (alizarin red)/MWCNTs/GC composite modified electrode[J].Journal of Wuhan Institute of Technology,2010,(11):18-21.[doi:10.3969/j.issn.16742869.2010.11.005]
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2010年11期
页码:
18-21
栏目:
化学与化学工程
出版日期:
2010-11-30

文章信息/Info

Title:
Voltammetric behavior of bisphenol A on poly (alizarin red)/
MWCNTs/GC composite modified electrode
文章编号:
16742869(2010)11001804
作者:
杨平; 李兰芳; 蔡惠; 金士威; 万其进*
武汉工程大学化工与制药学院,绿色化工过程省部共建教育部重点实验室,
湖北省新型反应器与绿色化学工艺重点实验室,湖北 武汉430074
Author(s):
YANG Ping;  LI Lanfang;  CAI Hui;  JIN Shiwei;  WAN Qijin
School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology,
Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan 430074, China
关键词:
茜素红; 碳纳米管; 修饰电极; 循环伏安法; 双酚A
Keywords:
alizarin red;  MWCNTs;  modified electrode;  cyclic voltammograms;  bisphenol A
分类号:
O657.1
DOI:
10.3969/j.issn.16742869.2010.11.005
文献标志码:
A
摘要:
在含茜素红的磷酸盐缓冲溶液中,用循环伏安法在制备好的碳纳米管修饰电极上电聚合茜素红膜,得到聚茜素红/碳纳米管复合修饰电极,并对复合修饰电极进行了电化学表征.研究了复合膜修饰电极对双酚A电催化作用的最佳条件.结果表明:双酚A的浓度在5.0×10-7~1.0×10-5 mol/L范围内与峰电流呈良好的线性关系;检测限可达5.0×10-8 mol/L.该复合修饰电极可作为电化学传感器用于双酚A的含量测定及环境水体中实际样品的分析.
Abstract:
Poly alizarin red film was prepared on multiwalled carbon nanotubes (MWCNTs) modified electrodes by cyclic voltammetry in phosphate buffer solution, and the modified electrode was characterized. The electrochemical behavior of bisphenol A on the poly (alizarin red)/MWCNTs/GC composite modified electrode (PAR/MWCNTs/GCE) was studied by cyclic voltammetry. Experiment result shows that the peak currents of linear sweep voltammograms are linear to the bisphenol A concentrations over the range of 5.0×10-7-1.0×10-5 mol/L. The detection limits is 5.0×10-8 mol/L. The PAR/MWCNTs/GCE can be used as electrochemical sensor for detection and quantitative analysis of bisphenol A and the sample in the environment.

参考文献/References:

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备注/Memo

备注/Memo:
张瑞收稿日期:20100619基金项目:国家自然科学基金资助项目(21075096)及湖北省教育厅科研基金资助项目(D20091501)作者简介:杨平(1986),男,湖北荆门人,硕士研究生.研究方向:生物电分析.指导老师:万其进,教授，硕士研究生导师.研究方向:生命分析化学、化学与生物传感器.*
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