|本期目录/Table of Contents|

[1]冯跃华.我国盐湖卤水提锂工程化现状及存在问题[J].武汉工程大学学报,2013,(05):9-14.[doi:103969/jissn16742869201305003]
 FENG Yue hua.Current status and existing problems in industrialization for lithiumextraction technology from salt lake brines in China[J].Journal of Wuhan Institute of Technology,2013,(05):9-14.[doi:103969/jissn16742869201305003]
点击复制

我国盐湖卤水提锂工程化现状及存在问题(/HTML)
分享到:

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2013年05期
页码:
9-14
栏目:
化学与化学工程
出版日期:
2013-05-31

文章信息/Info

Title:
Current status and existing problems in industrialization for lithiumextraction technology from salt lake brines in China
文章编号:
16742869(2013)05000906
作者:
冯跃华
化工部长沙设计研究院,湖南 长沙 410016
Author(s):
FENG Yuehua
Changsha Design and Research Institute of the Ministry of Chemical Industry,Changsha 410016,China
关键词:
盐湖碳酸锂工程化
Keywords:
salt lake lithium carbonate industrialization
分类号:
TD985
DOI:
103969/jissn16742869201305003
文献标志码:
A
摘要:
我国盐湖卤水中锂资源储量丰富,具有很好的开发利用前景.为了加快盐湖碳酸锂产业的发展,为我国提供紧缺的碳酸锂资源,我国科技工作者在盐湖提锂基础研究领域取得卓有成效的成果,但其产业化进程却发展缓慢,主要原因是过去对该领域重视不够、技术投入少,目前所采用工艺都存在各自的局限性:沉淀法受盐湖卤水性质影响较大,仅适合低镁锂比的卤水,应用范围受到限制;煅烧法能分离镁锂,但生产过程中产生氯化氢气体容易腐蚀设备,而且蒸发水量较大,能耗高,需对节能减排、环境保护和降低生产成本等方面进行改进;膜技术在反渗透浓缩过程中,膜易出现堵塞或损坏现象,且使用膜的成本较高,需要优化操作条件,稳定生产流程;离子吸附法处理卤水量大,其水耗、树脂消耗、动力消耗相应增大,特别是在淡水资源比较贫乏的地区受到一定程度的限制,同时在生产过程中导致树脂中毒和破碎等问题还需解决.所以,我们加强盐湖学基础研究的同时更应加快提锂技术的产业化进程研究.
Abstract:
The lithium resources are rich in China’s salt lake, and the utilizing value are high. To speed the development of lithium extraction industrialization in our country and provide more lithium resources, the researchers and developers have achieved fruitful achievements in the basic research of extracting lithium resources from salt lake brine. However, the degree of industrialization for lithium extraction technology is low. Because of less attention and investment in the past, the used techniques have their own limitations: the precipitation method has been limited by the property of salt lake brine, it is only suitable for the salt lakes with low ratio of magnesium to lithium; the calcinations method can separate magnesium and lithium, but the hydrogen chloride gas is produced which corrodes equipments, and the evaporated water is huge, the energy consumption is high, so we should improve energy saving, environmental protection and reduce production cost;the phenomenon that membrane is blocked and damaged appears easily in the membrane technology, which costs much, this method should be improved by improving the operating condition and stabilizing production process;the adsorption method need more consumption of water, resins and energy, it isn’t suitable to be used in areas lack of freshwater, meanwhile, the problems of resin poisoning and crushing should be solved. In a word, we should accelerate the study on lithium extraction industrialization, while we are strengthening basic research in this field.

参考文献/References:

[1]张文毓.锂产业技术经济综合分析\[J\].金属世界,2010(1):6467.Zhang Wenyu.Comprehensive Economic Analysis of Lithium Industrial Science and Technology\[J\].Metal World,2010(1):6467.(in Chinese)[2]刘元会,邓天龙.国内外从盐湖卤水中提锂工艺技术研究进展\[J\].世界科技研究与发展,2006,28(5):6975.Liu Yuanhui,Deng Tianlong.Progresses on the Process and Technique of Lithium Recovery from Salt Lake Brines Around the World\[J\].World Scitech R&D,2006,28(5):6975.(in Chinese)[3]郑绵平.论中国盐湖\[J\].矿床地质,2001,20(2):181189.Zheng Mianping.On Salibe Lakes of China\[J\].Mineral Deplsits,2001,20(2):181189.(in Chinese)[4]王卫东,曹茜.国内盐湖卤水提取碳酸锂生产工艺及现状\[J\].盐湖研究,2010,18(4):5261.Wang Weidong,CAO Qian. Production Process and Current Situation of Lithium Carbonate Extraction from Salt Lake Brine in China \[J\]. Journal of Salt Lake Research,2010,18(4):5261.(in Chinese)[5]申军,戴斌联.盐湖卤水锂矿资源开发利用及其展望\[J\].化工矿物与加工,2009,38(4):14,7.SHEN Jun,DAI Binlian. Status quo of salt lake brine lithium resources and prospect of its exploitation and application\[J\]. Industrial Minerals & Processing,2009,38(4):14,7.(in Chinese)[6]汪镜亮.卤水锂资源提锂现状\[J\].化工矿物与加工,1999,28(12):15.Wang Jingliang.The Present Status of Lithium Extraction from Libearing Brines\[J\].Industrial Minerals & Processing,1999,28(12):15.(in Chinese)[7]郑绵平,刘喜方.中国的锂资源\[J\].新材料产业,2007(8):1316.[8]郑春辉,董殿权,刘亦凡.卤水锂资源及其开发进展\[J\].盐业与化工,2006,35(6):3842.ZHENG Chunhui,DONG Dianquan,LIU Yifan. Lithium Resources and the Progress of Their Exploitation Techniques \[J\]. Journal of Salt and Chemical Industry,2006,35(6):3842.(in Chinese)[9]潘立玲,朱建华,李渝渝.锂资源及其开发技术进展\[J\].矿产综合利用,2002(2):2832.PAN Liling,ZHU Jianhua,LI Yuyu. Lithium Resources and the Progress of their Exploitation Techniques \[J\]. Multipurpose Utilization of Mineral Resources,2002(2):2832.(in Chinese)[10]钟辉,周燕芳,殷辉安.卤水锂资源开发技术进展\[J\].矿产综合利用,2003(1):2328.ZHONG Hui,ZHOU Yanfang,YIN Huian. Progress in Technology for Extracting Lithium from Libearing Brine Resources \[J\]. Multipurpose Utilization of Mineral Resources,2003(1):2328.(in Chinese)[11]李海民,程怀德,张全有.卤水资源开发利用技术述评\[J\].盐湖研究,2003,11(4):5256.LI Haimin,CHEN Huaide,ZHANG Quanyou. Evaluation of the Technologies of Comprehensive Utilization and Exploitation Salt Resource \[J\]. Journal of Salt Lake Research,2003,11(4):5256.(in Chinese)[12]袁俊生,纪志永.海水提锂研究进展\[J\].海湖盐与化工,2003,32(5):2933.YUAN Junsheng,JI Zhiyong. The Progress of Extracting Lithium from Seawater \[J\]. Sealake Salt and Chemical Industry,2003,32(5):2933. (in Chinese)[13]董庆洁,邵世香,郭星,等.离子筛型锂离子吸附剂的制备\[J\].海湖盐与化工,2005,34(6):68.Dong QingJie,SHAO ShiXiang,GUO Xing,et al. Preparation for Ionic Sieve Type Lithium Absorbent \[J\]. Sealake Salt and Chemical Industry,2005,34(6):68.(in Chinese)[14]常启明.世界卤水提锂发展概况\[J\].新疆有色金属,1994(4):4044.[15]Harben P, Edwards G.Minsal Lithium Carbonate:metamorphosis for lithium\[J\]. Industrial Minerals,1997(2):25.[16]肖明顺.智利锂公司( SCL) 简介\[J\].新疆有色金属,1997(1):4951.[17]乜 贞,卜令忠,郑绵平.中国盐湖锂资源的产业化现状——以西台吉乃乐盐湖和扎布耶盐湖为例\[J\].地球学报,2010,31(1):95101.NIE Zhen,BU Lingzhong,ZHENG Mianping. Lithium Resources Industrialization of Salt Lakes in China:a Case Study of the Xitaijinaier Salt Lake and the Zabuye Salt Lake \[J\]. Acta Geoscientica Sinica,2010,31(1):95101.(in Chinese)[18]余疆江,郑绵平,伍倩.富锂盐湖提锂工艺研究进展\[J\].化工进展,2013,32(1):1321.YU Jiangjiang,ZHENG Mianping,WU Qian. Research progress of lithium extraction process in lithiumcontaining salt lake \[J\]. Chemical Industry and Engineering Progress,2013,32(1):1321.(in Chinese)[19]黄维农,孙之南,王学魁,等.盐湖提锂研究和工业化进展\[J\].现代化工,2008,28(2):1417,19.HUANG Weinong,SUN Zhinan,WANG Xuekui,et al. Progress in industrialization for lithium extraction from salt lake \[J\]. Modern Chemical Industry,2008,28(2):1417,19.(in Chinese)[20]祝增虎,朱朝梁,温现明,等.碳酸锂生产工艺的研究进展\[J\].盐湖研究,2008,16(3):6472.ZHU Zenghu,ZHU Chaoliang,WEN Xianming,et al. Progress in Production Processof Lithium Carbonate \[J\]. Journal of Salt Lake Research,2008,16(3):6472.(in Chinese)[21]杨建元,夏康明.用高镁含锂卤水生产碳酸锂、氧化镁和盐酸的方法:中国,1724372\[P\].20060125.[22]宋彭生.盐湖及相关资源开发利用进展\[J\].盐湖研究,2000,8(1):116.SONG Pengsheng. Comprehensive Utilization of Salt Lake and Related Resources \[J\]. Journal of Salt Lake Research,2000,8(1):116.(in Chinese)[23]张逢星,李君,魏小兰,等.西部含锂、钾、镁、硼盐卤资源水盐体系相化学研究\[J\].盐湖研究,2002,10(3):2025.ZHANG Fengxing,LI Jun,WEI Xiaolan,et al. Study on the Phase Chemistry of the Saltwater System of Western Lithium,Potassium, Magnesium and Boron Containing Bittern Resources \[J\]. Journal of Salt Lake Research,2002,10(3):2025.(in Chinese)[24]马培华,邓小川,温现明.从盐湖卤水中分离镁和浓缩锂的方法.国家发明专利:CN 1626443\[P\],2005.[25]付浩.盐湖集团万吨级碳酸锂项目启动\[N\].中国化工报,20070626.[26]何力,陈儒庆,徐海运,等.用吸附法从察尔汗盐湖卤水中提取锂\[J\].湿法冶金,2003,22(3):118128.HE Li, CHEN Ruqing, XU Yunhai,et al. Extraction of Lithium from Chaerhan Saltlake Brine by Adsorption \[J\]. Hydrometallurgy of China,2003,22(3):118128.(in Chinese)

相似文献/References:

[1]马文梅,王营茹,明银安*,等.锂盐改性累托石处理染料废水[J].武汉工程大学学报,2012,(2):19.
 MA Wen\|mei,WANG Ying\|ru,MING Yin\|an,et al.Dye wastewater treatment by rectorite modified by lithium[J].Journal of Wuhan Institute of Technology,2012,(05):19.

备注/Memo

备注/Memo:
收稿日期:20130329作者简介:冯跃华(1959),女,湖南长沙人,教授级高级工程师.研究方向:盐湖化工工艺设计与咨询.第35卷第5期2013年05月武汉工程大学学报JWuhanInstTechVol35No5May2013
更新日期/Last Update: 2013-06-04