|本期目录/Table of Contents|

[1]张富青,陈晓霞,袁军,等.纳米碳酸钙对回收丙烯腈\|丁二烯\|苯乙烯共聚物性能的影响[J].武汉工程大学学报,2013,(09):59-63.[doi:103969/jissn167428692013090012]
　ZHANG Fu\|qing,Chen Xiao\|xia,Yuan Jun,et al.Effect of nano calcium carbonate on mechanical properties of recycled acrylonitrile\|butadiene\|styrene copolymer[J].Journal of Wuhan Institute of Technology,2013,(09):59-63.[doi:103969/jissn167428692013090012]
点击复制

纳米碳酸钙对回收丙烯腈\|丁二烯\|苯乙烯共聚物性能的影响(/HTML)
分享到：

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2013年09期
页码:
59-63
栏目:
资源与土木工程
出版日期:
2013-10-10

文章信息/Info

Title:
Effect of nano calcium carbonate on mechanical properties of recycled acrylonitrile\|butadiene\|styrene copolymer
文章编号:
16742869(2013)09005905
作者:
张富青1 ;  陈晓霞1; 袁军1; 江学良2*
1.武汉工程大学绿色化工过程省部共建教育部重点实验室，湖北 武汉 430074；2.武汉工程大学材料科学与工程学院，湖北 武汉 430074
Author(s):
ZHANG Fu\|qing1; Chen Xiao\|xia1;  Yuan Jun1;  JIANG Xue\|liang2
1.Key Laboratory for Green Chemical Process of Ministry of Education,Wuhan Institute of Technology,Wuhan 430074,China；2.School of Material Science and Engineering,Wuhan Institute of Technology,Wuhan 430074,China
关键词:
回收丙烯腈\|丁二烯\|苯乙烯共聚物; 纳米碳酸钙; 性能; 改性; 增容
Keywords:
recycled acrylonitrile\|butadiene\|styrene copolymer;  nano calcium carbonate;  property; modification;  compatibility
分类号:
TQ325
DOI:
103969/jissn167428692013090012
文献标志码:
A
摘要:
利用熔融共混方法制备出纳米碳酸钙/回收丙烯腈\|丁二烯\|苯乙烯复合材料，采用偶联剂对纳米碳酸钙表面改性，或加入增容剂马来酸酐接枝(丙烯腈/苯乙烯)共聚物（AS\|g\|MAH），得到力学性能较好的纳米碳酸钙/回收丙烯腈\|丁二烯\|苯乙烯复合材料.研究了纳米碳酸钙含量、偶联剂、增容剂AS\|g\|MAH对回收丙烯腈\|丁二烯\|苯乙烯（ABS）力学性能的影响.实验结果表明：与新料ABS相比，回收的ABS性能有所下降.纳米碳酸钙含量为ABS质量的2%，硅烷偶联剂含量为纳米碳酸钙质量的5%，或增容剂AS\|g\|MAH为纳米碳酸钙质量的2%时，回收ABS的力学性能最佳.扫描电镜显示加入增容剂AS\|g\|MAH后，纳米碳酸钙粒子能均匀混合在回收ABS中，且粒径分布较窄，分散性好；无增容剂时有纳米碳酸钙团聚粒子出现.
Abstract:
The nano calcium carbonate/recycled acrylonitrile\|butadiene\|styrene copolymer composites were prepared by the melt blending, and they have better mechanical properties after the surface of nano calcium carbonate was modified by the coupling agent, or compatibilizer maleic anhydride grafted acrylonitrile styrene copolymer (AS\|g\|MAH) was added. Effects of the content of nano calcium, coupling agent, compatibilizer AS\|g\|MAH on the mechanical properties of recycled acrylonitrile\|butadiene\|styrene (ABS) were studied. Experimental results show that the performance of recycled ABS decreases compared with the new ABS materials; recycled ABS has optimal mechanical properties as the content of nano calcium is 2% of ABS quality, the content of silane coupling agent and AS\|g\|MAH is 5% and 2% of nano calcium quality. Scanning electron microscopy shows that the addition of compatibilizer AS\|g\|MAH, nano calcium particles can be uniformly mixed in recycled ABS, and have narrow particle size distribution and good dispersion; nano calcium particles appear aggregation without the compatibilizer AS\|g\|MAH.

参考文献/References:

［1］赵国威，杜雪.试论ABS树脂技术发展趋势［J］.工业技术，2011，100（14）：21\|22. Zhao Guowei,Du Xue. Try to Talk about the Development Trend of ABS Resin Technology［J］. Industrial Technology,2011,100(14):21\|22.［2］陆德荣，何春霞.纳米复合材料微观结构研究进展［J］.工程塑料应用，2008，36(11)：81\|83.Lu Derong,He Chunxia.Development of Microscopic Study Cture Research on Nano\|Composite［J］. Engineering Plastics Application,2008,36(11):81\|83.［3］林志丹，黄珍珍，张宇，等.PP/改性纳米CaCO3复合材料力学性能与断裂形态研究［J］.工程塑料应用，2003，31（9）：7\|11.Lin Zhidan,Huang Zhenzhen,Zhang Yu, et al.Study on the Mechanical Properties and Fracture Morphology of PP/Nano\|CaCO3 Composites Modified with Reactive Monomer［J］. Engineering Plastics Application,2003,31(9):7\|11.［4］刘洋.无机纳米粒子改性聚合物研究［D］. 北京：北京化工大学，2005.Liu Yang.The Study on Inorganic Nanoparticles Modified Polymers［D］.Bei Jing:Beijing University of Chemical Technology,2005.［5］王旭，黄锐.PP/纳米级CaCO3复合材料性能研究［J］.中国塑料，1999，13（10）：22\|25.Wang Xu,Huang Rui.Study on Nano\|CaCO3 Reinforced Polypropylene［J］.China Plastics,1999,13(10):22\|25.［6］张雪琴，毋伟，曾晓飞,等.纳米CaCO3复合微粒对ABS性能的影响［J］.高分子材料科学与工程，2006，22(1)：87\|88.Zhang Xueqin,Wu Wei,Zeng Xiaofei,et al.Study on the Effect of Nano\|CaCO3 Composite Particle to ABS［J］.Polymer Materials Science and Engineering,2006,22(1):87\|88.［7］于建, 毛宇, 原栋, 等. PP/CaCO3复合体系的力学性能及其影响因素［J］.中国塑料，1999，13(9): 52\|57.Yu Jian,Mao Yu,Yuan Dong,et al. Mechanical Properties of PP/CaCO3 Composite System and Their Affecting Factors［J］.China Plastics,1999,13(9):52\|57.［8］陈可娟,于淼邈. AS\|g\|MAH增容PC/ABS合金的研究及应用［J］.工程塑料应用，2008,36(3):49\|52.Chen Kejuan,Yu Miaomiao.Study on AS\|g\|MAH Modified PC/ABS Alloy and its Application［J］. Engineering Plastics Application,2008,36(3):49\|52.［9］赫连青军，孙广平，刘畅，等.纳米CaCO3对通用塑料增韧增强的研究进展［J］.材料导报，2005，2(2)：109\|112.HELIAN Qingjun,Sun Guangping,Liu Chang,et al.Research Progress of Toughening Available Plastics with Nano\|CaCO3［J］.Materials Review,2005,2(2):109\|112.［10］Song J R, Shen Z G, Chen J F,et al.Study on the Microstructure and Mechanical Properties of Nano\|CaCO3\|ABS Composite ［J］.Polym Mater Sci & Eng, 2004,20(3):126\|128.［11］Fang Q Z，Wang T J，Li H M．Overload Effect on the Fatigue Crack Propagation of Pc/ABS Alloy［J］．Polymer，2007，4(22)：6691\|6706.［12］Jiang L,Lam Y C,Tam K C. Strengthening ABS with Nano\|sized and Micro\|sized Calcium Carbonate ［J］. Polymer,2005,23(1):67\|69.

相似文献/References:

备注/Memo

备注/Memo:
收稿日期：20130828基金项目：湖北省自然科学基金项目（2011CBD220）；武汉工程大学研究生创社基金项目作者简介：张富青（1975\|），女，湖北襄樊人，讲师，硕士.研究方向：功能高分子材料.*通讯联系人：江学良，男，博士，副教授.研究方向：功能高分子材料.
更新日期/Last Update: 2013-10-11