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[1]刘存成,马家玉,覃远航,等.表面活性剂对磷钾伴生矿中钾浸出的影响[J].武汉工程大学学报,2017,39(06):536-540.[doi:10. 3969/j. issn. 1674?2869. 2017. 06. 003]
 LIU Cuncheng,MA Jiayu,QIN Yuanhang,et al.Effect of Surfactants on Leaching of Potassium from Phosphorus-Potassium Associated Ore[J].Journal of Wuhan Institute of Technology,2017,39(06):536-540.[doi:10. 3969/j. issn. 1674?2869. 2017. 06. 003]
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表面活性剂对磷钾伴生矿中钾浸出的影响(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
39
期数:
2017年06期
页码:
536-540
栏目:
化学与化学工程
出版日期:
2017-12-30

文章信息/Info

Title:
Effect of Surfactants on Leaching of Potassium from Phosphorus-Potassium Associated Ore
文章编号:
1674 - 2869(2017)06 - 0536 - 05
作者:
刘存成1马家玉12覃远航12吴再坤1 2王存文12*
1. 武汉工程大学化工与制药学院,湖北 武汉 430205;2. 绿色化工过程教育部重点实验室(武汉工程大学),湖北 武汉 430205
Author(s):
LIU Cuncheng1 MA Jiayu12 QIN Yuanhang12 WU Zaikun12 WANG Cunwen12*
1. School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology,Wuhan 430205, China;2. Key Laboratory of Green Chemical Process (Wuhan Institute of Tchnology), Ministry of Education,Wuhan 430205, China
关键词:
表面活性剂磷钾伴生矿钾长石浸出率
Keywords:
surfactant phosphorus-potassium associated ore potassium K-feldspar leaching rate
分类号:
TF826.1;TQ443.5
DOI:
10. 3969/j. issn. 1674?2869. 2017. 06. 003
文献标志码:
A
摘要:
针对我国严重匮乏可溶性钾盐资源,而非可溶性钾资源却非常丰富,如磷钾伴生矿,因而探索从磷钾伴生矿中提取可溶性钾具有重要意义. 本文强化了磷钾伴生矿的酸浸过程,研究了在HCl-CaF2体系下,表面活性剂对磷钾伴生矿中钾浸出的影响. 结果表明:阴离子表面活性剂可以强化钾的浸出,阳离子表面活性剂对钾的浸出未产生明显影响,非离子表面活性剂会抑制钾的浸出. 通过筛选得到较佳的表面活性剂为十二烷基硫酸钠(SDS),其添加量为1.25 g/L,与未添加SDS的相比,钾浸出率提高了约8.5%,达到了98.01%.
Abstract:
China is rich in the insoluble potash ores such as phosphorus-potassium associated ore compared with the soluble hoevellite as a scarce resource in China. Thus, the extraction of soluble potassium from phosphorus-potassium associated ore has important significance. The intensification of the acid leaching process of phosphorus-potassium associated ore was investigated in this paper. The effect of surfactants on the leaching of potassium from phosphorus-potassium ore in HCl-CaF2 media was studied. It was found that anion surfactants could enhance the dissolution fraction of potassium. Cationic surfactants has not obvious effect and nonionic surfactants could inhibit the leaching of potassium. Moreover, sodium dodecyl sulfate (SDS) has the best effect in the selected surfactants. The leaching rate of potassium increases by 8.5% compared with no SDS and reaches 98.01% by adding 1.25 g/L SDS.

参考文献/References:

[1] ZHANG Y F,MA J Y,QIN Y H,et al. Ultrasound- assisted leaching of potassium from phosphorus- potassium associated ore[J]. Hydrometallurgy,2016,166:237-242. [2] MA J Y,ZHANG S,LR L, et al. The leaching kinetics and mechanism of potassium from phosphorus-potassium associated ore in hydrochloric acid at low temperature[J]. Separation Science and Technology,2017,52:132-141. [3] SIS H,CHANDER S. Improving froth characteristics and flotation recovery of phosphate ores with nonionic surfactants[J]. Minerals Engineering,2003,16(7):587-595. [4] HUANG Z,HONG Z,SHUAI W,et al. Investigations on reverse cationic flotation of iron ore by using a Gemini surfactant:Ethane-1,2-bis(dimethyl-dodecyl- ammonium bromide)[J]. Chemical Engineering Journal,2014,257(6):218-228. [5] SINGH B P, BESRA L. The effect of flocculants and surfactants on the filtration dewatering of iron ore fines[J]. Separation Science & Technology,1997,32(13):2201-2219. [6] 陈宇,王琪,崔鹏. 表面活性剂对磷矿脱镁过程的影响[J]. 应用化工,2013,42(4):644-646. CHEN Y,WANG Q,CUI P. Effect of surfactants on the removal of magnesium impurities from phosphate ore[J]. Applied Chemical Industry,2013,42(4): 644-646. [7] 韩效钊,胡波,高新勤,等. 表面活性剂与钾长石提钾过程的相容性研究[J]. 矿产综合利用,2005(6):3-7. HAN X Z, HU B, GAO X Q, et al. Research on the compatibility of surfactants with extractive process of potassium from potash feldspar[J]. Multipurpose Utilization of Mineral Resources,2005(6):3-7. [8] 吴爱祥,艾纯明,王贻明,等. 表面活性剂强化铜矿石浸出[J]. 北京科技大学学报,2013,35(6):709-713. WU A X,AI C M,WANG Y M,et al. Surfactant accelerating leaching of copper ores[J]. Journal of University of Science and Technology Beijing, 2013, 35(6):709-713. [9] OWUSU G,DREISINGER D B,PETERS E.Effect of surfactants on zinc and iron dissolution rates during oxidative leaching of sphalerite[J].Hydrometallurgy,1995,38(3):315. [10] 段欢. 低温浸出提取磷钾伴生矿中钾的研究[D]. 武汉:武汉工程大学,2014. [11] 赵国玺,朱步瑶. 表面活性剂作用原理[M]. 北京:中国轻工业出版社,2003: 450-455. [12] LIN I J,SOMASUNDARAN P. Free-energy changes on transfer of surface-active agents between various colloidal and interfacial states[J]. Journal of Colloid & Interface Science,1971,37(4):731-743. [13] I·古尔戈努力,张兴仁,李长根. 不同类型长石的表面与整体分析比较及其对浮选过程的重要意义[J]. 国外金属矿选矿,2008(11):25-29. I·GU ER GE NU LI, ZHANG X R,LI C G. Analysis on the surface and overall of different types of feldspar with its significance to the flotation process[J]. Metallic Ore Dressing Abroad, 2008(11):25-29. [14] 赵莉,邓成龙,徐宝财. 表面活性剂的性能与应用(Ⅹ)——表面活性剂的吸附作用及其应用[J]. 日用化学工业,2014,44(10):550-554. ZHAO L, DENG C L, XU B C. Performance and applications of surfactants(Ⅹ) adsorption effect of surfactants and applications[J]. China Surfactant Detergent & Cosmetics, 2014,44(10):550-554. [15] 肖进新,赵振国. 表面活性剂应用原理[M]. 北京:化学工业出版社, 2000:550-555. [16] 刘贺. 浅谈非离子表面活性剂的特点与应用[J]. 皮革与化工,2012,29(2):20-26.LIU H. Application and character of non-ionic surfactant[J]. Leather and Chemicals,2012,29(2): 20-26. [17] 张爽,吕仁亮,王为国,等. 低温酸浸磷钾伴生矿提钾工艺研究[J]. 现代化工,2015(5):96-100. ZHANG S,L? R L,WANG W G,et al. Potassium extraction from phosphorus-potassium associated ore at low temperature[J]. Modern Chemical Industry,2015(5):96-100.

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备注/Memo

备注/Memo:
收稿日期:2017-04-16基金项目:湖北省教育厅科学技术研究计划青年人才项目(Q20151506)作者简介:刘存成,硕士研究生. E-mail:1052127804@qq.com*通讯作者:王存文,博士,教授,博士研究生导师. E-mail:wangcw0120@163.com
更新日期/Last Update: 2018-01-04