|本期目录/Table of Contents|

[1]周 含,王浩楠,罗晓锋,等.碳包覆二氧化锰/石墨烯复合凝胶的制备与性能[J].武汉工程大学学报,2019,(02):131-136.[doi:10. 3969/j. issn. 1674?2869. 2019. 02. 006]
 ZHOU Han,WANG Haonan,LUO Xiaofeng,et al.Preparation and Performances of Carbon-Coated Manganese Oxide/Graphene Composite Hydrogel[J].Journal of Wuhan Institute of Technology,2019,(02):131-136.[doi:10. 3969/j. issn. 1674?2869. 2019. 02. 006]
点击复制

碳包覆二氧化锰/石墨烯复合凝胶的制备与性能(/HTML)
分享到:

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2019年02期
页码:
131-136
栏目:
材料科学与工程
出版日期:
2019-04-18

文章信息/Info

Title:
Preparation and Performances of Carbon-Coated Manganese Oxide/Graphene Composite Hydrogel
文章编号:
20190206
作者:
周 含王浩楠罗晓锋喻湘华李 亮*
武汉工程大学材料科学与工程学院,湖北 武汉 430205
Author(s):
ZHOU HanWANG HaonanLUO XiaofengYU XianghuaLI Liang*
School of Materials Science and Engineering,Wuhan Institute of Technology, Wuhan 430205, China
关键词:
碳包覆二氧化锰石墨烯复合凝胶电化学性能
Keywords:
carbon coated manganese dioxide graphene composite hydrogel electrochemical property
分类号:
O633
DOI:
10. 3969/j. issn. 1674?2869. 2019. 02. 006
文献标志码:
A
摘要:
为了充分发挥二氧化锰与石墨烯的电化学性能,并实现二者的性能互补,先制备超长二氧化锰(L-MnO2)纳米线,再以多巴胺作为碳源,合成碳包覆超长二氧化锰(C@L-MnO2),再将C@L-MnO2与氧化石墨烯通过水热反应制备碳包覆超长二氧化锰/石墨烯(C@L-MnO2/G)复合凝胶。利用扫描电子显微镜表征L-MnO2与C@L-MnO2复合材料的微观结构,研究了不同含量的C@L-MnO2对于复合凝胶形成的影响。采用恒电流充放电法、交流阻抗法等方法表征了复合凝胶的电化学性能。与碳包覆普通二氧化锰与氧化石墨烯合成的复合凝胶,以及与未经碳包覆的超长二氧化锰与氧化石墨烯合成的复合凝胶相比,C@L-MnO2/G复合凝胶的电化学性能有明显提高。
Abstract:
To enhance the electrochemical properties of manganese dioxide and graphene,we first prepared the carbon coated ultra-long manganese dioxide composite material (C@L-MnO2) using ultra-long manganese dioxide (L-MnO2) as the precursor and dopamine as the carbon source,then the carbon coated ultra-long manganese dioxide/graphene(C@L-MnO2/G) composite hydrogel was synthesized by the hydrothermal reaction of C@L-MnO2 and graphene oxide (GO). The microstructure of L-MnO2 and C@L-MnO2 was observed by scanning electron microscopy. The effect of C@L-MnO2 on the formation of C@L-MnO2/G composite hydrogel was studied, and the electrochemical performance of the composite hydrogel was measured by galvanostatic charge-discharge and atternating current impedance method. Compared with the hydrogels prepared with C@MnO2/GO and L-MnO2/GO,the electrochemical performance of C@L-MnO2/G composite hydrogel is significantly improved.

参考文献/References:

1] ZHANG H H,YANG J H,LIAO Z Y,et al. One-pot synthesis of graphite/MnO2,hybrids and electrochemical supercapacitor performance on different substrates[J]. Journal of Materials Science Materials in Electronics,2018,29(16):13681-13686. [2] ZHANG Q Z,ZHANG D,MIAO Z C,et al. Research progress in MnO2-carbon based supercapacitor electrode materials[J]. Small,2018,14(24): 1702883(1)- 1702883(15). [3] XIE Y M,WANG L J,GUO Q Y,et al. Preparation of MnO2/porous carbon material with core-shell structure and its application in supercapacitor[J]. Journal of Materials Science: Materials in Electronics,2018,29(10):7957-7964. [4] JIAN X, LIU S Y,AGO Y Q,et al. Carbon-based electrode materials for supercapacitor: progress,challenges and prospective solutions[J]. Journal of Electrical Engineering,2016,4(2):75-87. [5] HSIEH C T,TZOU D Y,LEE W Y,et al. Deposition of MnO2,nanoneedles on carbon nanotubes and graphene nanosheets as electrode materials for electrochemical capacitors[J]. Journal of Alloys & Compounds,2016,660:99-107. [6] RAMEZANI M, FATHI M, MAHBOUBI F. Facile synthesis of ternary MnO2 /graphene nanosheets/carbon nanotubes composites with high rate capability for supercapacitor applications[J]. Electrochimica Acta,2015,174:345-355. [7] LIU M X,SHI M C,LU W J,et al. Core-shell reduced graphene oxide/MnOx@carbon hollow nanospheres for high performance supercapacitor electrodes[J]. Chemical Engineering Journal,2017,313:518-526. [8] SUN J L,ZHU J L,ZHAO X,et al. Fabrication and photoconductivity of macroscopically long coaxial structured Ag/Ag2S nanowires with different core-to-shell thickness ratios[J]. Nanotechnology,2011,22(3):35-44. [9] HASSAN S,SUZUKI M,EL-MONEIM A A. Synthesis of MnO2-chitosan nanocomposite by one-step electrodeposition for electrochemical energy storage application[J]. Journal of Power Sources,2014,246:68-73. [10] CAO Y L,XIAO L F,WANG W,et al. Reversible sodium ion insertion in single crystalline manganese oxide nanowires with long cycle life[J]. Advanced Materials,2011,23(28):3155-3160. [11] XU C J,WEI C G,LI B H,et al. Charge storage mechanism of manganese dioxide for capacitor application: effect of the mild electrolytes containing alkaline and alkaline-earth metal cations[J]. Journal of Power Sources,2011,196(18):7854-7859. [12] YAO W,WANG J,LI H,et al. Flexible α-MnO2,paper formed by millimeter-long nanowires for supercapacitor electrodes[J]. Journal of Power Sources,2014,247:824-830. [13] LI L P,ZHU J H,NIU Y L,et al. Efficient production of coaxial core-shell MnO@carbon nanopipes for sustainable electrochemical energy storage applications[J]. Acs Sustainable Chemistry & Engineering,2017,5(7):6288-6296. [14] ZHENG F C,XIA G L,YANG Y,et al. MOF-derived ultrafine MnO nanocrystals embedded in a porous carbon matrix as high-performance anodes for lithium-ion batteries[J]. Nanoscale,2015,7(21):9637-9645. [15] LIU Y S,SHI K Y,ZHITOMIRSKY I. Asymmetric supercapacitor,based on composite MnO2-graphene and N-doped activated carbon coated carbon nanotube electrodes[J]. Electrochimica Acta,2017,233:142- 150. [16] 朱珍妮,熊惠之,喻湘华,等. 氮掺杂石墨烯/聚苯胺复合凝胶的制备与性能[J]. 武汉工程大学学报,2017,39(5):455-460. [17] HUANG X,YIN Z Y,WU S X, et al. Graphene-based materials: synthesis,characterization,properties,and applications[J]. Small,2011,7(14):1876-1902. [18] 李亮,胡军,班兴明,等. 石墨烯的制备及表征 [J]. 武汉工程大学学报,2014,36(8):46-50.

相似文献/References:

[1]万其进*,廖华玲,刘义,等.石墨烯修饰电极同时测定邻苯二酚和对苯二酚[J].武汉工程大学学报,2013,(02):16.[doi:103969/jissn16742869201302004]
 WAN Qi jin,LIAO Hua ling,LIU Yi,et al.Simultaneous determination of catechol and hydroquinone?in graphene modified electrode[J].Journal of Wuhan Institute of Technology,2013,(02):16.[doi:103969/jissn16742869201302004]
[2]李亮,朱寒冰,喻丹,等.甲基橙掺杂聚吡咯氧化石墨烯复合材料[J].武汉工程大学学报,2013,(05):43.[doi:103969/jissn16742869201305009]
 LI Liang,ZHU Han bing,YU Dan,et al.Composites of polypyrrole/graphene oxide doped by methyl orange[J].Journal of Wuhan Institute of Technology,2013,(02):43.[doi:103969/jissn16742869201305009]
[3]李亮,胡军,班兴明,等.石墨烯的制备及表征[J].武汉工程大学学报,2014,(08):46.[doi:103969/jissn16742869201408008]
 LI Liang,HU Jun,BAN Xing ming,et al.Preparation and characterization of graphene[J].Journal of Wuhan Institute of Technology,2014,(02):46.[doi:103969/jissn16742869201408008]
[4]彭林峰,汪 洋,柳景亚,等.氢氧化铜/石墨烯复合材料的制备与表征[J].武汉工程大学学报,2015,37(08):41.[doi:10. 3969/j. issn. 1674-2869. 2015. 08. 008]
 ,,et al.Preparation and characterization of copper hydroxide/graphene composite[J].Journal of Wuhan Institute of Technology,2015,37(02):41.[doi:10. 3969/j. issn. 1674-2869. 2015. 08. 008]
[5]朱 芬,张新敏,佘 潇,等.氮掺杂石墨烯凝胶的制备与表征[J].武汉工程大学学报,2016,38(3):259.[doi:10. 3969/j. issn. 1674?2869. 2016. 03. 011]
 ZHU Fen,ZHANG Xinmin,SHE Xiao,et al.Preparation and Characterization of Nitrogen-Doped Grapheme Hydrogel[J].Journal of Wuhan Institute of Technology,2016,38(02):259.[doi:10. 3969/j. issn. 1674?2869. 2016. 03. 011]
[6]张子俊,李 慧,张媛媛,等.基于纳米钯/石墨烯增敏效应对双酚A的电化学检测[J].武汉工程大学学报,2017,39(01):5.[doi:10. 3969/j. issn. 1674?2869. 2017. 01. 002]
 ZHANG Zijun,LI Hui,ZHANG Yuanyuan,et al.Bisphenol A Based on Enhancement Effect of Palladium Nanoparticle/Graphene[J].Journal of Wuhan Institute of Technology,2017,39(02):5.[doi:10. 3969/j. issn. 1674?2869. 2017. 01. 002]
[7]吴生丽,刘 忆,孙艳娟,等.功能化石墨烯四溴双酚A的电化学传感研究[J].武汉工程大学学报,2017,39(05):432.[doi:10. 3969/j. issn. 1674?2869. 2017. 05. 005]
 WU Shengli,LIU Yi,SUN Yanjuan,et al.An Electrochemical Sensor for Tetrabromobisphenol A Determination Based on Functionalized Graphene[J].Journal of Wuhan Institute of Technology,2017,39(02):432.[doi:10. 3969/j. issn. 1674?2869. 2017. 05. 005]
[8]朱珍妮,熊惠之,喻湘华,等.氮掺杂石墨烯/聚苯胺复合凝胶的制备与性能[J].武汉工程大学学报,2017,39(05):455.[doi:10. 3969/j. issn. 1674?2869. 2017. 05. 009]
 ZHU Zhenni,XIONG Huizhi,YU Xianghua,et al. Preparation of Nitrogen-Doped Graphene/Polyaniline Composite Hydrogels and Their Performance[J].Journal of Wuhan Institute of Technology,2017,39(02):455.[doi:10. 3969/j. issn. 1674?2869. 2017. 05. 009]
[9]李 阳,邱唯楚,蔡 卓,等.聚吡咯/石墨烯复合水凝胶的制备与性能[J].武汉工程大学学报,2018,40(05):530.[doi:10. 3969/j. issn. 1674-2869. 2018. 05. 010]
 LI Yang,QIU Weichu,CAI Zhuo,et al.Preparation and Properties of Polypyrrole/Graphene Compoiste Hydrogels[J].Journal of Wuhan Institute of Technology,2018,40(02):530.[doi:10. 3969/j. issn. 1674-2869. 2018. 05. 010]
[10]李 亮,陈 浩,邱唯楚,等.水热法制备聚苯胺/石墨烯复合材料的研究[J].武汉工程大学学报,2019,(01):55.[doi:10. 3969/j. issn. 1674?2869. 2019. 01. 008]
 LI Liang,CHEN Hao,QIU Weichu,et al.Hydrothermal Preparation of Polyaniline/Graphene Composites[J].Journal of Wuhan Institute of Technology,2019,(02):55.[doi:10. 3969/j. issn. 1674?2869. 2019. 01. 008]

备注/Memo

备注/Memo:
收稿日期:2018-11-23基金项目:武汉工程大学第十届研究生创新基金(CX2018062)作者简介:周 含,硕士研究生。E-mail: 1275325302@qq.com*通讯作者:李 亮,博士,教授。E-mail: msell08@163.com引文格式:周含,王浩楠,罗晓锋,等. 碳包覆二氧化锰/石墨烯复合凝胶的制备与性能[J]. 武汉工程大学学报,2019,41(2):131-136.
更新日期/Last Update: 2019-04-20