|本期目录/Table of Contents|

[1]郑俊文,陈宇欣,周 红,等.软模板法合成具有一维纳米结构的聚苯胺[J].武汉工程大学学报,2019,(03):254-257.[doi:10. 3969/j. issn. 1674-2869. 2019. 03. 009]
 ZHENG Junwen,CHEN Yuxin,ZHOU Hong,et al.Synthesis of Polyaniline with One-Dimensional Nanostructure by Soft Template[J].Journal of Wuhan Institute of Technology,2019,(03):254-257.[doi:10. 3969/j. issn. 1674-2869. 2019. 03. 009]
点击复制

软模板法合成具有一维纳米结构的聚苯胺(/HTML)
分享到:

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2019年03期
页码:
254-257
栏目:
材料科学与工程
出版日期:
2019-06-20

文章信息/Info

Title:
Synthesis of Polyaniline with One-Dimensional Nanostructure by Soft Template
文章编号:
20190309
作者:
郑俊文陈宇欣周 红喻湘华李 亮*
武汉工程大学材料科学与工程学院,湖北 武汉 430205
Author(s):
ZHENG Junwen CHEN Yuxin ZHOU HongYU Xianghua LI Liang*
School of Materials Science and Engineering,Wuhan Institute of Technology,Wuhan 430205, China
关键词:
软模板法甲基橙聚苯胺一维纳米结构
Keywords:
soft template methyl orange polyaniline one-dimensional nanostructure
分类号:
O633
DOI:
10. 3969/j. issn. 1674-2869. 2019. 03. 009
文献标志码:
A
摘要:
采用软膜板自组装方法,以甲基橙为软模版、过硫酸铵为氧化剂,在酸性条件下合成聚苯胺。探究了反应温度、加料顺序对聚苯胺的微观形貌与导电性能的影响。利用傅里叶变换红外光谱、扫描电子显微镜、X射线衍射表征所得到具有一维纳米结构聚苯胺的结构与微观形貌,并且对其进行了电导率测试。实验结果表明,在低温下,先加入过硫酸铵,再加入苯胺单体,可得到长度达到6 μm、电导率达到8.67×10-1 S/cm的一维纳米结构聚苯胺。
Abstract:
Polyaniline was prepared using methyl orange as the soft template and ammonium persulfate as the oxidant in the acidic condition. Effects of reaction temperature and feeding order on the microstructure and conductivity of the prepared polyaniline were investigated. Fourier transform infrared spectroscopy,scanning electron microscopy and X-ray diffraction were used to characterize the structure and morphology of polyaniline with one-dimensional nanostructure. The electrical conductivities of the prepared polyaniline were measured. The experimental results show that one-dimensional polyaniline with the length of about 6 μm and the conductivity of 8.67×10-1 S/cm could be prepared by first adding ammonium sulfate and then aniline monomer at the low temperatures.

参考文献/References:

[1] SARAVANAN R ,SACARI E, GRACIA F, et al. Conducting PANI stimulated ZnO system for visible light photocatalytic degradation of coloured dyes[J]. Journal of Molecular Liquids,2016,221:1029-1033. [2] L? P X,ZHAO Y,LIU F F,et al. Fabrication of polyaniline/polyimide composite fibers with electrically conductive properties[J]. Applied Surface Science,2016,36:335-341. [3] 李洪懿,陈可可,翟丁,等. 导电材料在膜分离领域中的应用[J]. 科技导报,2015,33(14):18-23. [4] 朱珍妮,熊惠之,喻湘华,等. 氮掺杂石墨烯/聚苯胺复合凝胶的制备与性能[J]. 武汉工程大学学报,2017,39(5):455-460. [5] NIE G D,LU X F,ZHU Y,et al. Reactive template synthesis of inorganic/organic VO2@polyaniline coaxial nanobelts for high-performance supercapacitors[J]. Cheme Electro Chem,2017,4(5):1095-1100. [6] QIN Y Y,PENG Q Y, DING Y J ,et al. Lightweight,superelastic,and mechanically flexible graphene/polyimide nanocomposite foam for strain sensor application[J]. ACS Nano,2015,9(9):8933-8941. [7] XU Z X,ZHUANG X D,YANG C Q,et al. Nitrogen- doped porous carbon superstructures derived from hierarchical assembly of polyimide nanosheets[J]. Advanced Materials,2016,28(10):1981-1987. [8] NAKAMURA T,JAYANTY S. Poly(4-styrenesulfonate) templated polyaniline-carboxymethyl cellulose blend: morphology and surfaceresistivity of the spin-coated films[J]. Soft Materials,2016,14(4):309-315[9] 武泽林,熊惠之,喻湘华,等. 聚苯胺-多糖复合凝胶的制备及其染料吸附性能[J]. 武汉工程大学学报,2017,39(4):348-352. [10] GOTO H, YOKOO A. Redox active carbon materials from polyaniline: plasma carbonization,heat carbonization,and preparation of capacitors[J]. International Journal of Polymeric Materials and Polymeric Biomaterials,2015,64(12):637-640. [11] REGO L S, ANTONIO J L S, SILVA C H B, et al. Electrochemical template synthesis of adherent polyaniline thin films with tubular structure[J]. Journal of Solid State Electrochemistry,2016,20(4):983-991. [12] ZU X H,ZHANG Z,YI G B,et al. A novel density- controlled growth of vertical polyaniline nanowire arrays using diblock copolymer as a template[J]. Materials Express,2016,6(1):83-87. [13] GU Z J, ZHANG Q C, SHEN Q. Synthesis and comparison of polyaniline nanofibers templated by α-,β-and γ-cyclodextrin[J]. Journal of Polymer Research,2015,22(2):7(1)-7(4). [14] MIAO T T, LI Y J, ZHANG D M. Synthesis of ultralong polyaniline nanorods by magnetic nanoparticles as templates under external magnetic field[J]. Journal of Nanoscience and Nanotechnology,2016,16(6):5729-5733. [15] SILVA C P,SANTANDER-NELLI M,VERA-OYARCE C,et al. Polyaniline nanostructure electrode: morphological control by a hybrid template[J]. Journal of Solid State Electrochemistry,2016,20(4):1175-1180. [16] ZHOU K, HE Y, XU Q C, et al. A hydrogel of ultrathin pure polyaniline nanofibers: oxidant-templating preparation and supercapacitor application[J]. ACS Nano,2018,12(6):5888-5894. [17] CHOI I Y,LEE J,AHN H,et al. High-conductivity two-dimensional polyaniline nanosheets developed on ice surfaces[J]. Angewandte Chemie(International Edition),2015,54(36):10497-10501. [18] LIU P, YANG C, WANG X ,et al. Alignment of polyaniline nanofibers on 3-D templates: "hairy" hollow microspheres as high-performance pseudocapacitive materials[J]. Synthetic Metals,2015,199:263-269. [19] ABDOLAHI A, HAMZAH E, IBRAHIM Z, et al. Synthesis of uniform polyaniline nanofibers through interfacial polymerization[J]. Materials,2012,5(8):1487-1494. [20] RENYA DEVI P S, DEO M N, KAWADIYA S, et al. Evaluation of the effect of heating on the ion exchange capacity of polyaniline[J]. Synthetic Metals,2015,210:297-303. [21] CHEN G, L? Q F, ZHAO H B. SnO2-decorated graphene/polyaniline nanocomposite for a high- performance supercapacitor electrode[J]. Journal of Materials Science & Technology,2015,31(11):1101-1107.

相似文献/References:

备注/Memo

备注/Memo:
收稿日期:2018-12-10基金项目:湖北高校省级大学生创新创业训练计划项目(201810490010)作者简介:郑俊文,硕士研究生。E-mail: 646271877@qq.com*通讯作者:李 亮,博士,教授。E-mail: msell08@163.com引文格式:郑俊文,陈宇欣,周红,等. 软模板法合成具有一维纳米结构的聚苯胺[J]. 武汉工程大学学报,2019,41(3):254-257.
更新日期/Last Update: 2019-06-19