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[1]陈　洋,戴武斌*,胡　金,等.Ca1-3x/2Al2Si2O8：xEu3+荧光粉的发光和光温传感特性[J].武汉工程大学学报,2021,43(04):398-401.[doi:10.19843/j.cnki.CN42-1779/TQ.202002012]
　CHEN Yang,DAI Wubin*,HU Jin,et al.Luminescent Properties and Optical Temperature Sensing Characteristics of Ca1-3x/2Al2Si2O8：xEu3+ Phosphor[J].Journal of Wuhan Institute of Technology,2021,43(04):398-401.[doi:10.19843/j.cnki.CN42-1779/TQ.202002012]
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Ca1-3x/2Al2Si2O8：xEu3+荧光粉的发光和光温传感特性(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
43
期数:
2021年04期
页码:
398-401
栏目:
材料科学与工程
出版日期:
2021-08-31

文章信息/Info

Title:
Luminescent Properties and Optical Temperature Sensing Characteristics of Ca1-3x/2Al2Si2O8：xEu3+ Phosphor
文章编号:
1674 - 2869（2021）04 - 0398 - 04
作者:
陈　洋; 戴武斌*; 胡　金; 樊烨明; 黎　华; 徐　慢
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
CHEN Yang; DAI Wubin*; HU Jin; FAN Yeming; LI Hua; XU Man
School of Materials Science and Engineering，Wuhan Institute of Technology， Wuhan 430205， China
关键词:
Ca1-3x/2Al2Si2O8：xEu3+; 荧光粉; 发光性能; 温度传感; 上升时间
Keywords:
Ca1-3x/2Al2Si2O8：xEu3+;  phosphor;  optical property;  optical temperature sensing;  rise time
分类号:
O482.31
DOI:
10.19843/j.cnki.CN42-1779/TQ.202002012
文献标志码:
A
摘要:
为了探究稀土离子掺杂铝硅酸盐的光温特性，本文采用燃烧合成法制备了系列荧光粉材料Ca1-3x/2Al2Si2O8：xEu3+。X射线衍射结果表明掺杂Eu3+离子不会改变基质CaAl2Si2O8的晶体结构。荧光光谱结果表明该荧光粉在近紫外光区域具有较强吸收，当被波长为393 nm的近紫外光激发后，其最大特征发射峰为611 nm，且Eu3+离子的最佳掺杂浓度为0.05。利用上升时间测温法研究了CaAl2Si2O8：Eu3+荧光粉的光温传感特性，结果表明：随着Eu3+掺杂浓度的增加，上升时间单调递减，但当掺杂掺杂超过0.100时就会发生淬灭。Ca0.985Al2Si2O8：0.01Eu3+的相对灵敏度随温度的升高先增大后减小，并在520 K时达到最大值（0.024 K-1）。上述研究表明该荧光粉具备优异的温度传感性能，在测温领域具有广泛的应用前景。
Abstract:
To investigate the optical temperature characteristics of rare earth ion doped aluminosilicate，a series of phosphor materials Ca1-3x/2Al2Si2O8：xEu3+ were prepared by combustion synthesis. The X-ray diffraction results show that the doping of Eu3+ ions does not change the crystal structure of the matrix CaAl2Si2O8. Fluorescence spectroscopy results show that the phosphor has strong absorption in the near-ultraviolet region. When excited by near-ultraviolet light with a wavelength of 393 nm，the phosphor material exhibits the maximum characteristic emission peak at 611 nm，and the optimal doping concentration of Eu3+ ion is 0.05. The optical temperature sensing characteristics of CaAl2Si2O8：Eu3+ phosphors were studied by the rise time method. The results show that the rise time monotonously decreases with the increase of Eu3+ doping concentration，but quenching occurs when the doping concentration exceeds 0.100. The test results of Ca0.985Al2Si2O8：0.01Eu3+ show that the relative sensitivity increases first and then decreases with the increase of temperature，and reaches the maximum value of 0.024 K-1 at 520 K. The above research indicates that the phosphor has excellent temperature sensing performance and has broad application prospects in the field of temperature measurement.

参考文献/References:

［1］　DAI W B，LEI Y F，ZHOU J，et al. 2D photonic crystal layer assisted thiosilicate ceramic plate with red-emitting film for high quality w-LEDs ［J］. Journal of the American Ceramic Society，2017，100（11）：5174-5185. ［2］　DAI W B，HU J，SHI S W，et al. Optical properties of aluminosilicate phosphor for lighting and temperature sensing ［J］. Journal of Luminescence，2019，213：241-248. ［3］　周佳，戴武斌，黄柯，等. Ca3Ga2Ge3O12：Pr3+，Yb3+发光性能及其在染料敏化太阳能电池中的应用［J］. 武汉工程大学学报，2018，40（6）：632-636，640. ［4］　SINGH B P， PARCHUR A K，SINGH R K， et al. Structural and up-conversion properties of Er3+ and Yb3+ co-doped Y2Ti2O7 phosphors ［J］. Physical Chemistry Chemical Physics，2013，15（10）：3480-3489. ［5］　WADE S A， COLILINS S F， BAXTER G W. Fluorescence intensity ratio technique for optical fiber point temperature sensing［J］. Journal of Applied Physics，2003，94（8）：4743-4756. ［6］　WANG X F，LIU Q，BU Y Y，et al. Optical temperature sensing of rare-earth ion doped phosphors［J］. RSC Advances，2015，5（105）：86219-86236. ［7］　BRITES C D S， LIMA P P， SILVA N J O， et al. Thermometry at the nanoscale ［J］. Nanoscale，2012，4（16）：4799-4829. ［8］　TU X B， XU J S， LI M C， et al. Color-tunable upconversion luminescence and temperature sensing behavior of Tm3+/Yb3+ codoped Y2Ti2O7 phosphors ［J］. Materials Research Bulletin，2019，112：77-83. ［9］　ZHANG L F，LYU S Y，ZHANG Q J，et al. Dual-emitting film with cellulose nanocrystal-assisted carbon dots grafted SrAl2O4：Eu2+，Dy3+ phosphors for temperature sensing ［J］. Carbohydrate Polymers，2019，206：767-777. ［10］　WU J， CHENG X R， JIANG F C， et al. Optical temperature sensing properties of Er3+/Yb3+ co-doped LuVO4 up-conversion phosphors ［J］. Physica B：Condensed Matter，2019，561：97-102. ［11］　SONG H L， HAN Q， WANG C， et al. Optical temperature sensing properties of Sm3+ doped SrWO4 phosphor ［J］. Optical Materials，2018，78：402-406. ［12］　DAI W B，ZHOU J，HUANG K，et al. Investigation on structure and optical properties of down-conversion aluminosilicate phosphors CaAl2Si2O8：Ce/Tb/Yb ［J］. Journal of Alloys and Compounds，2019，786：662-667. ［13］　XU J，MURATA D，KATAYAMA Y，et al. Cr3+/Er3+ co-doped LaAlO3 perovskite phosphor：a near-infrared persistent luminescence probe covering the first and third biological windows ［J］. Journal of Materials Chemistry B，2017，5（31）：6385-6393. ［14］　SINGH D K，DHANANJAY K MANAM J. Efficient dual emission mode of green emitting perovskite BaTiO3：Er3+ phosphors for display and temperature sensing applications ［J］. Ceramics International，2018，44（9）：10912-10920. ［15］　RANSON R M，EVANGELOU E， THOMAS C B. Modeling the fluorescent lifetime of Y2O3：Eu［J］. Applied Physics Letters，1998，72（21）：2663-2664. ［16］　VALEUR B， BERBERAN-SANTOS M N. A brief history of fluorescence and phosphorescence before the emergence of quantum theory［J］. Journal of Chemical Education，2011，88（6）：731-738.

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备注/Memo

备注/Memo:
收稿日期：2020-02-20基金项目：湖北省技术创新专项（2016ACA160）；武汉工程大学博士启动基金（16QD28）作者简介：陈　洋，硕士研究生。E-mail： yangchen@wit.edu.cn*通讯作者：戴武斌，博士，特聘教授。E-mail： wubin.dai@wit.edu.cn引文格式：陈洋，戴武斌，胡金，等. Ca1-3x/2Al2Si2O8：xEu3+荧光粉的发光和光温传感特性［J］. 武汉工程大学学报，2021，43（4）：398-401.
更新日期/Last Update: 2021-08-07