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[1]周　佳,张佳乐,戴武斌*,等.碱土氯硅酸盐荧光粉的研究进展[J].武汉工程大学学报,2019,(03):242-247.[doi:10. 3969/j. issn. 1674-2869. 2019. 03. 007]
　ZHOU Jia,ZHANG Jiale,DAI Wubin*,et al.Progress in Alkaline Earth Silicate Chloride Phosphor[J].Journal of Wuhan Institute of Technology,2019,(03):242-247.[doi:10. 3969/j. issn. 1674-2869. 2019. 03. 007]
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碱土氯硅酸盐荧光粉的研究进展(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2019年03期
页码:
242-247
栏目:
材料科学与工程
出版日期:
2019-06-20

文章信息/Info

Title:
Progress in Alkaline Earth Silicate Chloride Phosphor
文章编号:
20190307
作者:
周　佳; 张佳乐; 戴武斌*; 黄　珂; 徐　慢; 王树林
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
ZHOU Jia; ZHANG Jiale; DAI Wubin*; HUANG Ke; XU Man; WANG Shulin
School of Materials Science and Engineering， Wuhan Institute of Technology， Wuhan 430205， China
关键词:
碱土氯硅酸盐; 荧光粉; 白光发光二极管; 研究进展
Keywords:
alkaline earth silicate chloride;  phosphor;  white light-emitting diode;  research progress
分类号:
O482.31
DOI:
10. 3969/j. issn. 1674-2869. 2019. 03. 007
文献标志码:
A
摘要:
开发性能优异的新型发光二极管（LED）用荧光粉一直是发光材料领域的重要挑战。介绍了近年来几种重要碱土氯硅酸盐荧光粉的研究进展，发现该体系荧光粉材料具有特殊的晶体结构和丰富的阳离子格位，当被不同的稀土离子激活时可呈现出多种发光性能，非常适合作为白光LED用荧光粉。但是该体系荧光粉制备方法大多采用高温固相法合成，并且主要集中在以Eu2+等少数稀土离子作为激活剂的荧光粉上。因此，寻找低成本、高功效的制备方法，加强对其它碱土氯硅酸盐基质材料或稀土离子复合体系荧光粉的研究，对于未来白光LED领域的发展和突破具有重要意义。
Abstract:
The development of novel phosphors for ultraviolet light-emitting diodes（LEDs） with excellent performance has always been a significant challenge in the field of luminescent materials. The research progress in several important alkaline earth chlorosilicate phosphors was introduced in detail. It is found that alkaline earth silicate chloride phosphors have special crystal structure and rich cationic sites，enabling them to exhibit different luminescent properties when activated by a variety of dopants. Thus they are suitable to be used in white LEDs. However，the preparation methods of this kind of phosphors are mainly based on the high temperature solid state reaction，and phosphors with only a few kinds of rare earth ions were used as activators，such as Eu2+. Therefore low-cost， high-efficiency preparation methods and the further study on other alkaline earth chlorosilicate matrixes or rare earth ions co-doped phosphors are of great significance for the future development and breakthrough of white LEDs.

参考文献/References:

［1］　GEORGE N C， DENAULT K A， SESHADRI R . Phosphors for solid-state white lighting［J］. Annual Review of Materials Research，2013，43（1）：481-501. ［2］　KWAG D S，SO S H，BAEK S M. Study on thermal and structural stability of high power light-emitting diode lighting system ［J］. Journal of Nanoscience and Nanotechnology，2014，14（5）：3564-3568. ［3］　SMET P F，PARMENTIR A B，POELMAN D. Selecting conversion phosphors for white light-emitting diodes ［J］. Journal of the Electro Chemical Society，2011，158（6）：37-54. ［4］　KRAMES M R，SHCHEKIN O B，MUELLER-MACH R，et al. Status and future of high-power light-emitting diodes for solid-state lighting ［J］. Journal of Display Technology，2007，3（2）：160-175. ［5］　DEVAKUMAR B， GUO H， ZENG Y J， et al. A single-phased warm-white-emitting K3Y（PO4）2：Dy3+, Sm3+ phosphor with tuneable photoluminescence for near-UV-excited white LEDs ［J］. Dyes and Pigments，2018，157：72-79. ［6］　DAI W B，LEI Y F，ZHOU J，et al. 2D photonic crystal layer assisted thiosilicate ceramic plate with red-emitting film for high quality w-LEDs ［J］. Journal of the American Ceramic Society，2017，100（11）：5174-5185. ［7］　WEI Z R，ZHENG K，HOU T X，et al. Synthesis and luminescent properties of Sr4-xSi3O8Cl4：xEu3+ red phosphor by hydrothermal method ［J］. International Journal of Applied Ceramic Technology，2018，15（1）：118-124. ［8］　DEVI L L，BASAVAPOORNIMA C，VENKATRAMU V， et al. Synthesis of Ca2SiO4： Dy3+ phosphors from agricultural waste for solid state lighting applications ［J］. Ceramics International，2017，43（18）：16622-16627. ［9］　YE S， XIAO F， PAN Y X， et al. Phosphors in phosphor-converted white light-emitting diodes：recent advances in materials，techniques and properties ［J］. Materials Science and Engineering R-Reports，2011，71（1）：1-34. ［10］　WANG F， WANG W， JIN Y. Photoluminescence properties of Ce3+/Mn2+ doped calcium zirconium silicate phosphors with energy transfer for white LEDs ［J］. Ceramics International，2016，42（15）：16626-16632. ［11］　DEWANGAN P， BISEN D P， BRAHME N， et al. Studies on thermoluminescence properties of alkaline earth silicate phosphors ［J］. Journal of Alloys and Compounds，2018，735：1383-1388. ［12］　ZHOU W J，OU Y Y，LI X H，et al. Luminescence and cationic-size-driven site selection of Eu3+ and Ce3+ ions in Ca8Mg（SiO4）4Cl2 ［J］. Inorganic Chemistry，2018，57（23）：14872-14881. ［13］　SHARMA K，TALWAR G，MOHARIL S V，et al. Luminescence of Ce3+ in some compounds in the system CaO-SiO2-CaCl2 ［J］. Journal of Luminescence，2017，188：168-171. ［14］　BAGINSKIY I， LIU R S. Significant improved luminescence intensity of Eu2+ -doped Ca3SiO4Cl2 green phosphor for white LEDs synthesized through two-stage method ［J］. Journal of the Electrochemical Society，2009，156（5）：G29-G32. ［15］　CI Z P，SUN M X，JIANG X J，et al. Photoluminescence，thermal properties and energy transfer mechanism of Ce3+， Tb3+ co-activated Sr8Si4O12Cl8 phosphor ［J］. Materials Research Bulletin，2014，60：279-284. ［16］　SUN J F，ZHANG Y D. Ce3+-activated Ca8Zn（SiO4）4Cl2：a novel near-ultraviolet converting blue-emitting chlorosilicate phosphor for white light-emitting diodes ［J］. Materials Letters，2016，181：4-7. ［17］　ZHOU J J，TENG Y，LIU X F，et al. Intense infrared emission of Er3+ in Ca8Mg（SiO4）4Cl2 phosphor from energy transfer of Eu2+ by broadband down-conversion ［J］. Optics Express，2010，18（21）：21663-21668. ［18］　LIU W，HAO Z D，ZHANG X，et al. Near UV and blue-based LED fabricated with Ca8Zn（SiO4）4Cl2：Eu2+ as green-emitting phosphor ［J］. Optical Materials，2011，34（1）：261-264. ［19］　LIU W，HAO Z D，ZHANG X，et al. Intense green/yellow emission in Ca8Zn（SiO4）4Cl2：Eu2+,Mn2+ through energy transfer for blue-LED lighting ［J］. Journal of Luminescence，2011，131（11）：2387-2390. ［20］　LI J F， ZHANG H R， LEI B F ，et al. Luminescent properties of green long-lasting Ca8Mg（SiO4）4Cl2：Eu2+，from Ca2SO4：Eu3+ and MgCl2 at low temperature［J］. Physica B：Condensed Matter，2013，430（12）：31-35. ［21］　LEI B F， SHA L， ZHANG H R， et al. Preparation and luminescence properties of green-light-emitting afterglow phosphor Ca8Mg（SiO4）4Cl2： Eu2+［J］. Solid State Sciences，2010，12（12）：2177-2181. ［22］　GUO C F， LI M， XU Y， et al. A potential green- emitting phosphor Ca8Mg（SiO4）4Cl2： Eu2+ for white light emitting diodes prepared by sol-gel method ［J］. Applied Surface Science，2011，257（21）：8836-8839. ［23］　ZHU G，WANG Y H，CI Z P，et al. Ca8Mg（SiO4）4Cl2：Ce3+,Tb3+：a potential single-phased phosphor for white- light-emitting diodes ［J］. Journal of Luminescence，2012，132（2）：531-536. ［24］　DING W J，WANG J，ZHANG M，et al. Luminescence properties of new Ca10（Si2O7）3Cl2： Eu2+ phosphor［J］. Chemical Physics Letters，2007，435（4）：301-305. ［25］　LI Z M，GAO S K，CHEN X X，et al. Synthesis and luminescence properties of green phosphors Ca6Sr4（Si2O7）3Cl2：Eu2+ for white light emitting diodes ［J］. Journal of Luminescence，2012，132（6）：1497-1500. ［26］　SUN J F，SHI Y M，ZHANG W L，et al. Luminescent and thermal properties of a new green emitting Ca6Sr4（Si2O7）3Cl2： Eu2+ phosphor for near-UV light- emitting diodes ［J］. Materials Research Bulletin，2012，47（2）：400-404. ［27］　SUN J F，ZHANG W L，SHI Y M，et al. Green-emitting Ca6Sr4（Si2O7）3Cl2：Eu2+phosphors for white light-emitting diodes ［J］. Journal of the Electrochemical Society，2012，159（1）：J5-J12. ［28］　XIE X Z，ZHONG M Z，LI X Q，et al. Red，green and blue-violet emission coexistence in white-light-emitting Ca3SiO4Cl2：Bi3+,Li+,Eu2+,Eu3+phosphor ［J］. Ceramics International，2017，43（2）：1937-1942. ［29］　LI X Q， XIE X Z， WEI H T， et al. Tunable luminescence and energy transfer in Ca3SiO4Cl2：Ce3+,Li+,Mn2+,Eu2+ phosphors［J］. Luminescence，2017，32（6）：1025-1030. ［30］　ZHAO X， LI Z S， YU T， et al. Tunable orange red phosphors：S2--doped high temperature phase Ca3SiO4Cl2： Eu2+ for solid-state lighting ［J］. RSC Advances，2012，3（6）：1965-1969. ［31］　SHEN W Q， ZHU Y W， WANG Z L. Luminescent properties of Ca3SiO4Cl2 co-doped with Ce3+ and Eu2+ for near-ultraviolet light-emitting diodes［J］. Luminescence，2015，30（8）：1409-1412. ［32］　CHEN J S. Effects of Ce doping on the luminescent property of Ca3SiO4Cl2：Eu phosphor for green lighting ［J］. Luminescence，2015，30（2）：159-162. ［33］　LIU C M，QI Z M，MA C G， et al. High light yield of Sr8（Si4O12）Cl8： Eu2+ under X-ray excitation and its temperature-dependent luminescence characteristics ［J］. Chemistry of Materials，2014，26（12）：3709-3715. ［34］　LIU C M，ZHANG S，LIU Z Y，et al. A potential cyan-emitting phosphor Sr8（Si4O12）Cl8： Eu2+ for wide color gamut 3D-PDP and 3D-FED ［J］. Journal of Materials Chemistry C，2013，1（7）：1305-1308.

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备注/Memo

备注/Memo:
收稿日期：2018-08-30基金项目：湖北省技术创新专项（2016ACA160）；武汉工程大学博士启动基金（16QD28）；武汉工程大学第九届研究生教育创新基金（CX2017013）作者简介：周　佳，硕士研究生。E-mail： jia.zhou@wit.edu.cn*通讯作者：戴武斌，博士，特聘教授。E-mail： wubin.dai@wit.edu.cn引文格式：周佳，张佳乐，戴武斌，等. 碱土氯硅酸盐荧光粉的研究进展［J］. 武汉工程大学学报，2019，41（3）：242-247，253.
更新日期/Last Update: 2019-06-19