|本期目录/Table of Contents|

[1]马茹萍,罗 剑,吕 彦,等.锰氧化物/聚苯胺/石墨烯三元复合电极材料的制备及电化学性能[J].武汉工程大学学报,2023,45(06):641-646.[doi:10.19843/j.cnki.CN42-1779/TQ.202210027]
　MA Ruping,LUO Jian,Lü Yan,et al.Preparation and Electrochemical Performance of Manganese Oxide/Polyaniline/Graphene Ternary Composite Electrode Materials[J].Journal of Wuhan Institute of Technology,2023,45(06):641-646.[doi:10.19843/j.cnki.CN42-1779/TQ.202210027]
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锰氧化物/聚苯胺/石墨烯三元复合电极材料的制备及电化学性能(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
45
期数:
2023年06期
页码:
641-646
栏目:
材料科学与工程
出版日期:
2023-12-28

文章信息/Info

Title:
Preparation and Electrochemical Performance of Manganese Oxide/
Polyaniline/Graphene Ternary Composite Electrode Materials
文章编号:
1674 - 2869（2023）06 - 0641 - 06
作者:
马茹萍; 罗 剑; 吕 彦; 黄华波*
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
MA Ruping; LUO Jian; Lü Yan; HUANG Huabo*
School of Materials Science and Engineering，Wuhan Institute of Technology，Wuhan 430205，China
关键词:
锰氧化物; 聚苯胺; 石墨烯; 超级电容器
Keywords:
manganese oxide;  polyaniline;  graphene;  supercapacitor
分类号:
O633
DOI:
10.19843/j.cnki.CN42-1779/TQ.202210027
文献标志码:
A
摘要:
首先通过苯胺气体与高锰酸钾水溶液之间的气-液界面反应合成了二氧化锰/聚苯胺（MP）纳米复合材料，然后将其与氧化石墨烯（GO）水溶液混合并进行水热处理，最终得到了锰氧化物/聚苯胺/石墨烯（MPG）三元纳米复合电极材料。通过X射线衍射、拉曼光谱和扫描电子显微镜分析了产物的物质组成、结构和微观形貌。电化学测试结果表明，MPG具有较高的比电容（251 F/g，1 A/g）、理想的倍率性能（扫描速率由10 mV/s增大到200 mV/s时的比电容保持率为55%）和长循环寿命（5 A/g电流密度下，循环充放电5 000次后，其比电容保持率为81%），证实通过三元复合的方法可以有效改善锰基超级电容器电极材料的电化学性能。

Abstract:
Manganese dioxide/polyaniline （MP） composite was synthesized via a gas-liquid interfacial reaction between aniline gas and potassium permanganate aqueous solution，and then the ternary composite electrode material of manganese oxide/polyaniline/graphene （MPG） was prepared through hydrothermal treatment of the mixture of MP and graphene oxide. The chemical composition and structure were characterized by X-ray diffraction and Raman spectroscopy，and the micromorphology was observed by scanning electron microscopy. The results of electrochemical measurement manifest that MPG possesses a high specific capacitance of 251 F/g at 1 A/g，a favorable capacitance retention of 55% with scan rates from 10 up to 200 mV/s，and a high capacitance retention of 81% after 5 000 charging/discharging cycles at 5 A/g，demonstrating that the electrochemical performance of manganese-based electrode materials for supercapacitor can be effectively improved by the ternary composite method.

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备注/Memo

备注/Memo:
收稿日期：2022-10-25
基金项目：国家级大学生创新创业训练计划项目（202110490005）；湖北省自然科学基金（2021CFB507）
作者简介：马茹萍，本科生。E-mail：prma001@163.com
*通讯作者：黄华波，博士，副教授。E-mail：hbhuang@wit.edu.cn
引文格式：马茹萍，罗剑，吕彦，等. 锰氧化物/聚苯胺/石墨烯三元复合电极材料的制备及电化学性能［J］. 武汉工程大学学报，2023，45（6）：641-646，654.
更新日期/Last Update: 2023-12-25