|本期目录/Table of Contents|

[1]李亮,赵旭,李强.一种合成片状结构聚苯胺的新方法[J].武汉工程大学学报,2011,(07):56-59.
　LI Liang,ZHAO Xu,LI Qiang.Facile method for synthesis of sheetlike polyaniline[J].Journal of Wuhan Institute of Technology,2011,(07):56-59.
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一种合成片状结构聚苯胺的新方法(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2011年07期
页码:
56-59
栏目:
材料科学与工程
出版日期:
2011-08-30

文章信息/Info

Title:
Facile method for synthesis of sheetlike polyaniline
文章编号:
16742869(2011)07005604
作者:
李亮; 赵旭; 李强
武汉工程大学 材料科学与工程学院，湖北 武汉 430074
Author(s):
LI Liang;  ZHAO Xu;  LI Qiang
School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430074, China
关键词:
聚苯胺; 模板; 掺杂剂; 酸度
Keywords:
PANI;  template;  dopant;  acidity
分类号:
O633
DOI:
-
文献标志码:
AAdoi:10.3969/j.issn.16742869.2011.07.016
摘要:
利用无模板法成功合成了片状结构的聚苯胺.用扫描电镜，红外和X射线衍射对产物进行了表征.通过对聚苯胺形貌和结构的研究，分析了聚苯胺的形成机理.而且对影响实验的参数，包括掺杂剂的种类，单体浓度，反应酸度进行了系统的研究.
Abstract:
?Polyaniline (PANI) micro/nanosheets are successfully synthesized by a templatefree method. Scanning electron microscopy, FTIR spectroscopy and XRD are used to characterize the products. By investigating the morphologies and chemical structures of the PANI micro/nanosheets, a possible formation mechanism is proposed. In addition, the effects of experimental parameters, such as the kind of dopant, concentration of aniline, and acidity of reaction system, have been systematically investigated.

参考文献/References:

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［2］Wang Y G, Li H Q, Xia Y Y. Ordered whiskerlike polyaniline grown on the surface of mesoporous carbon and its electrochemical capacitance performance ［J］. Adv Mater， 2006（18）： 26192623.
［3］Li G C, Zhang C Q, Peng H R, et al. Hollow selfdoped polyaniline micro/nanostructures: microspheres, and nanotubes ［J］. Macromol. Rapid Commun, 2008(29)： 19541958.
［4］Adhikari A, Claesson A, Pani J, et al. Electrochemical behavior and anticorrosion properties of modified polyaniline dispersed in polyvinylacetate coating on carbon steel ［J］. Electrochim Acta, 2008(53): 42394247.
［5］Chen C C, Hwang S R, Li W H, et al. Enhanced electroluminescence of polymer lightemitted diodes with direct polyaniline synthesized anodes ［J］. Polym J， 2002（34）： 271274.
［6］Li G C, Jiang L,? Peng H R. Onedimensional polyaniline nanostructures with controllable surfaces and diameters using vanadic acid as the oxidant ［J］. Macromolecules,2007(40): 78907894.
［7］Sadek A Z, Wlodarski W, Shin K, et al. A polyaniline/WO3 nanofiber compositebased ZnO hydrogen gas sensor ［J］. Synth Met, 2008(158): 2932.
［8］Zhang H B, Wang J X, Zhou Z B, et al. Preparation of nanostructured polyaniline and its superamphiphilic behavior ［J］. Macromol. Rapid Commun, 2008(29): 6873.
［9］Huang J X, Kaner R B. Syntheses and applications of conducting polymer polyaniline nanofibers ［J］. Angew Chem Int Ed, 2004(43): 58175821.
［10］Han J, Song J P, Guo R. Nanostructurebased leaflike polyaniline in the presence of an amphiphilic triblock copolymer ［J］. Adv Mater， 2007（19）： 29932999.

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